A clean stream of alkanes from renewable biomass resources is obtained through aqueous-phase reforming in a single reactor. Alkanes are produced from biomass-derived sorbitol through a bifunctional pathway (see scheme) that involves the dehydration of sorbitol on acid sites (SiO2/Al2O3) and hydrogenation of intermediates on a metal catalyst under a H2 atmosphere. Hydrogen is produced from sorbi...

In this issue of Chem Catalysis , Jinchang Fan et al. demonstrate that Cu atoms confined in ultrathin 2D metallic Ru nanosheets (Ru 11 NSs) favor bi-coordinated adsorption O∗ species to reduce the activation energy barrier for a facile C–H bond cleavage C 1 oxygenates (CH 3 OOH and CH OH) with 99% selectivity.

T R I B O L O G Y & L U B R I C A T I O N T E C H N O L O G Y W W W . S T L E . O R G wide range of approaches have been undertaken to determine how to reduce emissions from automotive engines. in a previous TLT article, the development of the homogeneous charge compression ignition (hCCi) engine was discussed. When used in place of a conventional gasoline engine, an hCCi engine can produce a 1...

The oxidative and nonoxidative conversion of ethylene in a dielectric barrier discharge the presence water with formation predominantly unsaturated compounds (acetylene, butene, butadiene) has been studied. efficiency argon is shown comparison its oxidation by air into oxygenates. A simple theoretical estimate energy loss electrons feed gas mixture kinetic calculations make it possible to expla...

The article considers measures aimed at improving the environmental situation of large cities by reducing harmful effects exhaust gases generated during operation road transport. It is substantiated that a direct increase in friendliness motor gasoline most promising approach to toxicity gases. This can be achieved dissolved hydrocarbon (C4H10 and iso-C4H10) metals (Pb, Fe, Mn) gasoline; facili...

global air pollution is a serious threat caused by excessive use of fossil fuels for transportation. despite the fact that diesel fuel is a big environmental pollutant as it contains different hydrocarbons, sulphur and crude oil residues, it is yet regarded as a highly critical fuel due to its wide applications. nowadays, biodiesel as a renewable additive is blended with diesel fuel to achieve ...

Cobalt pi-complexes, previously described in the literature and specially synthesized and characterized in this work, were used as catalysts in homogeneous oxidation of organic compounds with peroxides. These complexes contain pi-butadienyl and pi-cyclopentadienyl ligands: [(tetramethylcyclobutadiene)(benzene)cobalt] hexafluorophosphate, [(C₄Me₄)Co(C₆H₆)]PF₆ (1); diiodo(carbonyl)(pentamethylcyc...

Abstract manganese lipoxygenase (Mn-LO) oxygenates 18:3n-3 and 18:2n-6 to bis-allylic 11S-hydroperoxy fatty acids, which are converted to 13R-hydroperoxy fatty acids. Other unsaturated C(16)-C(22) fatty acids, except 17:3n-3, are poor substrates, possibly because of ineffective enzyme activation (Mn(II)-->Mn(III)) by the produced hydroperoxides. Our aim was to determine whether unsaturated C(16...

This study reports evidence for catalytic deoxygenation of alkanols, alkanals, and alkanediols on dispersed Cu clusters with minimal use of external H(2) and with the concurrent formation of new C-C and C-O bonds. These catalysts selectively remove O-atoms from these oxygenates as CO or CO(2) through decarbonylation or decarboxylation routes, respectively, that use C-atoms present within reacta...