Background Cerium oxide (CeO2) is a technologically important material due to its properties and applications in several areas that range from engineering to biological sciences. Despite the hydrothermal microwave method versatility, its crystallization kinetics has low speed when the processing temperatures are below 300°C which are the desired conditions for soft chemistry processes [1,2]. At...

Cerium oxide nanoparticles (CeO2 NPs) have been shown to have significant interactions in plants. Previous study reported the specific-species phytotoxicity of CeO2 NPs by lettuce (Lactuca sativa), but their physiological impacts and vivo biotransformation are not yet well understood, especially in relative realistic environment. Butterhead lettuce were germinated and grown in potting soil for ...

we have performed a density functional theory investigation on the structural and electronic properties of pristine and nitrogen-doped tio2 anatase nanoparticles as the adsorbents for removal and degradation of hydrazine molecules in the environment. we have presented the most stable adsorption configurations and examined the interaction of hydrazine molecule with these doped and undoped nanopa...

The potential toxicity and accumulation of engineered nanomaterials (ENMs) in agricultural crops has become an area of great concern and intense investigation. Interestingly, although below-ground vegetables are most likely to accumulate the highest concentrations of ENMs, little work has been done investigating the potential uptake and accumulation of ENMs for this plant group. The overall obj...

In this work, the WGS performance of a conventional Ni/CeO2 bulk catalyst is compared to that of a carbon-supported Ni-CeO2 catalyst. The carbon-supported sample resulted to be much more active than the bulk one. The higher activity of the Ni-CeO2/C catalyst is associated to its oxygen storage capacity, a parameter that strongly influences the WGS behavior. The stability of the carbon-supported...

The sintering behavior of gadolinia-doped ceria powders was studied by the master sintering curve (MSC). Dilatometric analyses of powders produced by a soft chemical method were performed to provide the experimental data set for the construction of the MSC. The assumed model provided good fittings of the MSC and the activation energy for the sintering of Ce1-xGdxO3-d, with x = 0, 0.05, 0.1, and...

Integrated CO2 capture and methanation (ICCM) is attracting more attention to promote the reduction of emission. This work developed applied a set combined materials using Ru/CeO2 as catalyst physically mixed Li, Na, K-doped MgO adsorbent for ICCM process. The influences morphologies CeO2 (rod, particle, cube) in are investigated explicitly terms conversion CH4 yield. Compared with cube morphol...

In the present work, Al2O3-CeO2 composite nanopowders were synthesized via co-precipitation method. The sinterability of the synthesized powders was investigated. The results showed that the transformation of transition phases of alumina to α-Al2O3 takes place at 1200 °C. TEM images showed that the powders was composed of nanoparticles in the range of 30−70 nm. The densification of composites s...

Density functional plane-wave calculations have been performed to investigate a series of ceria nanoparticles (CeO2-x)(n), n Ce3+ reduction have been accounted for through the use of an effective on-site Coulomb repulsive interaction within the so-called DFT+U approach. Twelve nanoparticles of up to 2 nm in diamet...