To unlock the widespread use of block copolymers as photonic pigments, there is an urgent need to consider their environmental impact (cf. microplastic pollution). Here we show how inverse glass architecture can enable biocompatible bottlebrush (BBCPs), which otherwise lack refractive index contrast needed for a strong response. A library pigments produced from poly(norbornene-graft-polycaprola...

Gel sheets prepared from high-viscosity aqueous dispersions of hydrolyzed starch-polyacrylonitrile graft copolymers absorb several hundred times their own weight in water. Viscosity of the disperSiOns can be . reduced to low levels by mechanical shear before the films are cast to give solutions which yield water'soluble .films. These soluble films can be readily cross-linked to again form highl...