The development of a simple and rapid multielemental speciation method is described with the ultimate goal to simultaneously determine various organometallic compounds of mercury, lead and tin (inorganic mercury, methylmercury, trimethyllead, triethyllead, monobutyl-, dibutyl- and tributyltin) in natural water samples. The analytical method consists on the ethylation with NaBEt4, simultaneous h...

Thermal treatment of pasteurisation is the most widely used stabilisation method for packed green table olives. In present work, influence on composition volatile compounds in Spanish-style olives was studied. To this aim, two thermal processes (P1 = 85 °C 7 min; P2 15 min) were evaluated by comparing contents pasteurised with those unpasteurised Volatiles analysed, both olive juice and cover b...

Honey volatiles exhibit a potential role in distinguishing honeys as a function of botanical origin, but heating of honey generates artefacts such as compounds of Strecker degradation and Maillard reaction products. This short review is focused on the most recently applied methods for honey volatiles fingerprinting (without generation of thermal artefacts): headspace extraction (dynamic headspa...

Headspace solid-phase microextraction (HS-SPME) and ultrasonic solvent extraction (USE), followed by GC-MS/FID, were applied for monitoring the nectar (NE)/honey-sac (HoS)/honey (HO) pathways of the headspace, volatiles, and semi-volatiles. The major NE (4 varieties of Citrus unshiu) headspace compounds were linalool, α-terpineol, 1H-indole, methyl anthranilate, and phenylacetonitrile. Correspo...

in this paper, the possibility of using a new ordered nanoporous carbon as a new fiber in headspace solid phase microextraction (hs-spme) to determine of mononitrotoluenes (mnts) in waste water is demonstrated. the structural order and textural properties of the ordered nanoporous carbon were studied by x ray diffraction (xrd), scanning electron microscopy (sem) images and nitrogen adsorption i...

A new method for extraction and analysis of ethanol and methanol in human whole blood, urine and saliva samples based on headspace solid phase microextraction (SPME) using silver sulfide (Ag(2)S) and polyvinyl chloride (PVC) coated on silver wire is described. Unlike commercial fibers, which are coated on fused silica, the proposed fiber has a metallic base to which the coating adheres very str...

Mushrooms are sources of food, medicines, and agricultural means. Not much is reported in the literature about wild species of the Mediterranean flora, although many of them are traditionally collected for human consumption. The knowledge of their chemical constituents could represent a valid tool for both taxonomic and physiological characterizations. In this work, a headspace-solid-phase micr...

The extraction and quantitative analysis of low molar mass compounds in polymers is an analytical challenge. It is also important from a practical point of view because the low molar mass compounds in time will migrate from the polymers into the surrounding environment. It is especially important to gain knowledge about the migrating compounds in applications such as medical implants, packaging...

Volatile organic compounds (VOCs) from uninfested and infested broccoli plant samples with green peach aphid Myzus persicae were investigated by headspace solid microextraction (HS-SPME) combined gas chromatography mass spectrometry (GC-MS). Overall, 25 identified in plants. The HS-SPME GC-MS analysis of the volatiles described differences between samples. Based on peak area analysis, VOCs sign...

Analyses of key odorous polyfunctional volatile thiols in wines (3-mercaptohexanol (3-MH), 3-mercaptohexylacetate (3-MHA), and 4-mercapto-4-methyl-2-pentanone (4-MMP)) are challenging due to their high reactivity and ultra-trace concentrations, especially when using conventional gas-chromatography electron impact mass spectrometry (GC-EI-MS). We describe a method in which thiols are converted t...