The process of reductive dissolution of α-Fe2O3, Ba-hexaferrite, α-FeOOH, γ-Fe2O3, γ-FeOOH, and ferrihydrite can be monitored continuously by abrasive stripping voltammetry and chronoamperometry to obtain information about homogeneity of reactivity and about the particle size of the pure phases and mixtures. Phase parameters (rate constant and charge transfer coefficient) and the geometrical fa...