Metal-organic frameworks (MOFs) are crystalline hybrid framework materials composed of inorganic metal “nodes” bridged by rigid organic linkers, thereby featuring exceptionally high surface areas and porosities. Despite the successful synthesis of a plethora of intricate framework topologies, a major objective in current MOF chemistry is the extension of pore sizes from the micropore (> 2 nm) t...

Zeolites are crystalline hydrated tektoalumosilicates consisting of a three-dimensional framework of SiO4 4and AlO4 5tetrahedra linked through shared oxygen atoms. The heulandite group of zeolites including clinoptilolite are the most abundant zeolites in nature 1, 2 . Clinoptilolite is used in a wide range of industrial and agricultural applications, particularly in animal nutrition. Dietary i...

Zeolites containing Zn in their frameworks are promising materials for ion-exchange and catalysis because of their unique ion-exchange capabilities and characteristic Lewis acidity. However, expensive organic compounds often required in their synthesis can prevent their practical uses. Here, a facile organic-free synthesis route for new zincoaluminosilicate zeolites having MOR topology, in whic...

Zeolites with their unique properties find applications in various fields, including medicine, agronomy, ecology, production of detergents and drying agents, a number industrial processes. Among zeolites, mordenite is particularly widespread because its high silica/alumina ratio, which allows it to resist exposure temperatures acidic gases liquids. Mordenite commercially available as natural mi...

Hierarchical zeolites have attracted more and attention due to their excellent diffusion mass transfer performance. However, synthesis of most hierarchical requires long-chain organic templates, which could increase preparation cost. Here, ZSM-5 were successfully prepared with simple templates (triethylenetetramine) in a rotating oven. Besides structure, the crystal size also decreased when the...

The database of prospective zeolites (www. hypotheticalzeolites.net) has been screened in search of feasible zeolites. Previous criteria of zeolite feasibility have been reviewed, based on descriptors such as energy, density, average and distribution of ring sizes, and more importantly that of Li et al. (LID criteria) presented recently [Angew. Chem. Int. Ed. 2013, 52, 1673], based on Si–O, O.....

Surfactant-templating is one of the most versatile and useful techniques to implement mesoporous systems into solid materials. Various strategies based on various interactions between surfactants and solid precursors have been explored to produce new structures. Zeolites are invaluable as size- and shape-selective solid acid catalysts. Nevertheless, their micropores impose limitations on the ma...