نتایج جستجو برای: hydridoaminocarboxylato iridium iii complexes
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We report herein the synthesis and application of a series of novel cyclometalated iridium(III) complexes 1-3 bearing a rhodamine-linked NˆN ligand for the detection of Cu(2+) ions. Under the optimised conditions, the complexes exhibited high sensitivity and selectivity for Cu(2+) ions over a panel of other metal ions, and showed consistent performance in a pH value range of 6 to 8. Furthermore...
A new class of cationic iridium(III) complexes of the form [(C(∧)N)2Ir(N(∧)N)][PF6] is reported, where C(∧)N = cyclometallating 2-phenylpyridinato, ppy, or 2-(2,4-difluorophenyl)-5'-methylpyridinato, dFMeppy, and N(∧)N = guanidyl-pyridine, gpy, or -pyrazine, gpz, as the ancillary ligand. A large blue-shift in the emission coupled with a 7-to-9 fold enhancement in photoluminescence quantum yield...
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