We report here new approaches for the direct intercalation of layered double hydroxides (LDHs) from carbonate-LDHs by using various organic acids as proton sources de-carbonation.

Aggregates containing certain constituents can react with alkali hydroxides in concrete. The reactivity is potentially harmful only when it produces significant expansion (Mather 1975). This alkali-aggregate reactivity (AAR) has two forms—alkali-silica reaction (ASR) and alkali-carbonate reaction (ACR, sometimes called alkali-carbonate rock reaction, or ACRR). ASR is more often a concern than A...

Despite obvious differences in morphology, substratum chemistry and the electrolyte in which they form, accumulations of iron corrosion products have the following characteristics in common: stratification of iron oxides/hydroxides with a preponderance of α-FeOOH (goethite) and accumulation of metals. Bacteria, particularly iron-oxidizing and sulfate-reducing bacteria have been identified in so...

In the course of searching for a suitable marker for studying protein oxidation, we have successfully elucidated the structures of three valine hydroperoxides, i.e. beta-hydroperoxyvaline, (2S,3S)-gamma-hydroperoxyvaline and (2S,3R)-gamma-hydroperoxyvaline, which are novel products of protein oxidation. The corresponding valine hydroxides were obtained by sodium borohydride reduction [Fu, Hick,...

Fluoride is one of the anionic contaminants which is found in excess in surface or groundwater because of geochemical reactions or anthropogenic activities such as the disposal of industrial wastewaters. Among various methods used for defluoridation of water such as coagulation, precipitation, membrane processes, electrolytic treatment, ion-exchange, the adsorption process is widely used. It of...

Caustic ingestion can produce a progressive and devastating injury to the oesophagus and stomach. Caustic material ingestion is most frequently encountered in children who accidentally swallowed caustic materials or in adults who ingested caustic materials for suicidal purposes.1,2 Alkaline caustics and acids are the commonest chemicals implicated in caustic burns. Stricture formation with inab...

Submitted for the MAR13 Meeting of The American Physical Society Computational NMR, IR/RAMAN calculations in sodium pravastatin: Investigation of the Self-Assembled Nanostructure of Pravastatin-LDH (Layered Double Hydroxides) Systems1 PHILIPPE PETERSEN, VANESSA CUNHA, MARCOS GONÇALVES, HELENA PETRILLI, VERA CONSTANTINO, Universidade de Sao Paulo, INSTITUTO DE F́ıSICA, DEPARTAMENTODE F́ıSICA DEMAT...