Aromatic carbonyl compounds such as 10-methylacridone form the Lewis acid complexes including paramagnetic and redox active Lewis acids. The fluorescence energies of the Lewis acid complexes are well correlated with the O2*--Lewis acid complexes derived from the gzz-values of the ESR spectra of the superoxide anion-Lewis acid complexes, thus providing a quantitative measure of the Lewis acidity.

The thermosolutal instability problem in a horizontal layer of an elasticoviscous nanofluid in porous medium is considered. Walters’ (model B') fluid model is employed to describe the rheological behavior of the nanofluid and for the porous medium, the Darcy model is employed. From the linear stability analysis based upon normal modes analysis method, the dispersion relation accounting for the ...

Matrix proteolysis is thought to play a crucial role in several stages of tumor progression, including angiogenesis, and the invasion and metastasis of tumor cells. We investigated the specific role of gelatinase A (matrix metalloproteinase 2) on these events using gelatinase A-deficient mice. In these mice, tumor-induced angiogenesis was suppressed according to dorsal air sac assay. When B16-B...

Turbulent lean premixed dodecane/air flames are simulated in a doubly-periodic domain using detailed kinetics and transport over a range of Karlovitz number. We observe extensive thickening of thermal profiles through the flames that increases with turbulent intensity. The high Lewis number of the flames acts to suppress wrinkling of the flame resulting in considerably lower turbulent flame spe...

Hydrogen production by metal particles in water could provide a renewable energy cycle, if its reaction kinetics is accelerated. Here, ab initio molecular dynamics simulation reveals rapid hydrogen production from water by a cluster (or superatom) consisting of a magic number of aluminum atoms, Al{n} (for instance, n=12 or 17). We find a low activation-barrier mechanism, in which a pair of Lewi...