Gas generation (namely, the volume swelling of battery, or called the gassing) is a common phenomenon of the degradation of battery performance, which is generally a result of the electrolyte decomposition occurring during the entire lifespan of Li-ion batteries no matter whether the battery is in service or not. Abuse conditions such as overcharging and overheating make the gassing worse or ev...

The fabrication of very high-aspect ratio 3D carbon microelectrodes for Li-Ion batteries is presented. Using a pyrolysis process under inert conditions, thick layers of patterned SU-8 photoresist (up to 600 μm in height) are converted into carbon. The micro-structures resulting from this process are used as anode for a Li-Ion battery. A detailed explanation on how to create SU-8 structures of a...

The cost of Energy Storage System (ESS) for frequency regulation is difficult to calculate due to battery’s degradation when an ESS is in grid-connected operation. To solve this problem, the influence mechanism of actual operating conditions on the life degradation of Li-ion battery energy storage is analyzed. A control strategy of Li-ion ESS participating in grid frequency regulation is constr...

State-of-charge (SOC) estimations of Li-ion batteries have been the focus of many research studies in previous years. Many articles discussed the dynamic model’s parameters estimation of the Li-ion battery, where the fixed forgetting factor recursive least square estimation methodology is employed. However, the change rate of each parameter to reach the true value is not taken into consideratio...

Lithium dendrite growth in Li-ion batteries is one of the most dangerous phenomena because it can cause inner short circuits and thermal runaways. However, nucleation dendrites are difficult to predict their complex behaviors, which depend on several factors such as charging conditions electrode-design parameters. In this study, a comprehensive mathematical model has been developed for Li-depos...

State of health (SOH) prediction in Li-ion batteries plays an important role in intelligent battery management systems (BMS). However, the existence of capacity regeneration phenomena remains a great challenge for accurately predicting the battery SOH. This paper proposes a novel prognostic framework to predict the regeneration phenomena of the current battery using the data of a historical bat...

For control and estimation tasks in battery management systems, the benchmark Li-ion cell electrochemical pseudotwo-dimensional (P2D) model is often reduced to the Single Particle Model (SPM). The original SPM consists of two electrodes approximated as spherical particles with spatially distributed Li-ion concentration. However, the Li-ion concentration states in these two-electrode models are ...

We study the Li clustering process on graphene and obtain the geometry, nucleation barrier, and electronic structure of the clusters using first-principles calculations. We estimate the concentration-dependent nucleation barrier for Li on graphene. While the nucleation occurs more readily with increasing Li concentration, possibly leading to the dendrite formation and failure of the Li-ion batt...

BACKGROUND LiCoO2 is one of the most used cathode materials in Li-ion batteries. Its conventional synthesis requires high temperature (>800 °C) and long heating time (>24 h) to obtain the micronscale rhombohedral layered high-temperature phase of LiCoO2 (HT-LCO). Nanoscale HT-LCO is of interest to improve the battery performance as the lithium (Li+) ion pathway is expected to be shorter in nano...

Lithium-ion battery performance is strongly influenced by the ionic conductivity of the electrolyte, which depends on the speed at which Li ions migrate across the cell and relates to their solvation structure. The choice of solvent can greatly impact both the solvation and diffusivity of Li ions. In this work, we used first-principles molecular dynamics to examine the solvation and diffusion o...