An analytical cluster wetting model is developed, based on minimization of an expression for the free energy, for solid-liquid equilibrium coexistence states in clusters. For given materials’ characteristic interfacial energies of the solid and liquid phases, the model relates the fraction of the solid-phase area wetted by the liquid to the volume fraction of the two phases. Equilibrium coexist...

We discuss the growth process of a crystalline phase out of a metastable over-compressed liquid that is brought into contact with a crystalline substrate. The process is modeled by means of molecular dynamics. The particles interact via the Lennard-Jones potential and their motion is locally thermalized by Langevin dynamics. We characterize the relaxation process of the solid-liquid interface, ...

liquid-liquid equilibrium data for the (water + lactic acid + 2-ethy-1-hexanol) ternary system in t=298.2k and p=1atm were determined and tie- lines related to equilibrium data has been drawn in the phases diagram . the reliability of the experimental tie-line data for this system was as confirmed by using the hand and othmer –tobias correlations. the tie-line data were correlated by means of t...