Parameters from single-component isotherm models were used in multicomponent isotherm models to predict the aqueous phase sorption of trichloroethylene (TCE) in the presence of tetrachloroethylene (PCE) in four zeolites, Tenax, and three natural solids. The Langmuir, the Polanyi-Dubinin, and the Freundlich or the Langmuir-Freundlich isotherm models were used to simulate single-component sorptio...

Modification of chitosan biopolymer was achieved by grafting (3-phenyl-1H-pyrazole-4-carbaldehyde) by the Schiff base reaction to synthesize a new chitosan derivative (ChD). The formation of the product was confirmed by FTIR, XRD and CNMR analysis. The grafted molecule provided additional nitrogen bearing groups as binding sites. The new derivative was used to investigate the removal of Cr (VI)...

Ala~ntct--Tbe performance characteristics of two activated carbons and eight synthetic adsorbents are compared. The comparison addresses both the equilibrium capacities and mass transport properties of the adsorbents. A new empirical adsorption isotherm is employed for description of adsorption equilibrium data. A' predictive mathematical model is used for forecasting adsorption bed performance...

In this study, the Langmuir adsorption isotherm has been coupled with activity coefficient models for prediction of surface tension of single and mixed electrolyte solutions. Various activity models such as Meissner, Pitzer and extended UNIQUAC have been used and coupled with Langmuir adsorption isotherm. The model parameters were determined through mathematical optimization using experimental ...

The ability of coconut husk to remove methylene blue from solution was investigated. Factors such as initial dye concentration, contact time, adsorbent dosage and pH of solution were studied. Results show that Langmuir isotherm can be successfully applied to the methylede blue coconut husk system and that coconut husk is a suitable adsorbent for such a dye. Maximum adsorption capacity is 99 mg ...

This study explored the feasibility of using granular ferric hydroxide as adsorbent for the removal of NO3-N. Optimum conditions for NO3-N removal were found to be pH 5.0 and equilibrium time 80min. The equilibrium sorption isotherm was better described by Langmuir sorption isotherm model. The maximum sorption capacity of granular ferric hydroxide was 4.254mg/g at 298K. A comparison of four kin...

in this study adsorption of 1-chloro-4-nitrobenzene (cnb) from aqueous solutions onto multi-walled carbon nanotubes (mwcnts) was surveyed. the effect of some key parameters such as ph (2-10), carbon nanotubes dosage (0.02-0.1 mg/250ml), cnb concentration (2- 16 mg/l), and temperature (20,30,40,50°c) were investigated. the results showed that, the variation of initial ph and cnb concentration ex...

The objectives of this study were [1] to conduct some experimental tests of the surface precipitation adsorption model, and [2] to work on the development of a simple yet widely applicable approach to modelling adsorption of inorganic ions on oxide surfaces. The latter represents the first portion of our continuing effort to develop a data base for adsorption of inorganic contaminants in oxide ...

By allowing the surface charge of one surface to affect the adsorption equilibrium of the other, we establish the existence of a long-range attractive interaction between two identical surfaces in an electrolyte containing polyvalent counterions with a mean-field Poisson-Boltzmann approach. A Stern electrostatic condition from linearization of the mass-action adsorption isotherm is used to capt...

The potential use of Croatian natural zeolite clinoptilolite as alternative adsorbents for removal of enrofloxacin (ENRO) as model pollutant was studied in a batch system. The influence of contact time and initial ENRO concentration on the sorption process was investigated. The percentage removal of ENRO from aqueous phase decreased with an increase in initial concentration. The experimental da...