Formate dehydrogenase H from Escherichia coli contains selenocysteine (SeCys), molybdenum, two molybdopterin guanine dinucleotide (MGD) cofactors, and an Fe4S4 cluster at the active site and catalyzes the two-electron oxidation of formate to carbon dioxide. The crystal structures of the oxidized [Mo(VI), Fe4S4(ox)] form of formate dehydrogenase H (with and without bound inhibitor) and the reduc...

The electroreduction of water for sustainable hydrogen production is a critical component of several developing clean-energy technologies, such as water splitting and fuel cells. However, finding a cheap and efficient alternative catalyst to replace currently used platinum-based catalysts is still a prerequisite for the commercialization of these technologies. Here we report a robust and highly...

Isotope anomalies provide important information about early solar system evolution. Here we report molybdenum isotope abundances determined in samples of various meteorite classes. There is no fractionation of molybdenum isotopes in our sample set within 0.1 h and no contribution from the extinct radionuclide Tc at mass 97 (Tc/Mo < 3× 10). Instead, we observe clear anomalies in bulk iron meteor...

Methods Following a standardized physical exam using sterile gloves and a sterile stethoscope, bacterial contamination of the following regions were assessed using contact plates: stethoscope diaphragm, stethoscope tube, fingertips, thenar region, hypothenar region and back of physician’s dominant hand. Total aerobic colony count (ACC) were determined on digital photographs using a counting tool.

INTRODUCTION Food-borne infections and intoxications remain one of the most important public health issues globally, both in developing and in developed countries. Numbers of reported outbreaks of food-borne diseases and diseased people are constantly growing. For instance, a total of 320,000 of cases of food-borne diseases, caused by only 6 most prevalent bacterial pathogens (non-typhoidal Sal...

In the present study, nanocrystalline Ni50Al50-xMox (X = 0, 0.5, 1, 2.5, 5) intermetallic compound was produced through mechanical alloying of nickel, aluminum, and molybdenum powders. AlNi compounds with good and attractive properties such as high melting point, high strength to weight ratio and high corrosion resistance especially at high temperatures have attracted the attention of many rese...

Trace elements mean elements present at low concentrations (mg kg-1 or less) in agroecosystems. Some trace elements, including copper (Cu), zinc (Zn), manganese (Mn), iron (Fe), molybdenum (Mo), and boron (B) are essential to plant growth and are called micronutrients. Except for B, these elements are also heavy metals, and are toxic to plants at high concentrations. Some trace elements, such a...

Unlike graphene, the existence of bandgaps (1-2 eV) in the layered semiconductor molybdenum disulphide, combined with mobility enhancement by dielectric engineering, offers an attractive possibility of using single-layer molybdenum disulphide field-effect transistors in low-power switching devices. However, the complicated process of fabricating single-layer molybdenum disulphide with an additi...

Structures operating at high temperatures and exposed to aggressive gaseous media are made of low-alloy molybdenum TsM-10 of the system Mo-Al-B, TsM-6 of the system Mo-Zr-B and TsM-12 of the system Mo-Zr-Hf-B [1, 2]. Alloy TsM-10 is commercially pure molybdenum deoxidized by aluminium and boron. Alloy TsM-6 is alloyed with up to 0.2 wt. % zirconium and TsM-12, is alloyed with up to 0.03 wt. % z...