Mordenite (H-MOR) catalysts were synthesized by a hydrothermal method, and silver-modified mordenite (Ag-MOR) prepared ion exchange with AgNO3 at different concentrations. The performance of these in the carbonylation dimethyl ether (DME) to methyl acetate (MA) was also evaluated. characterized Ar adsorption/desorption, XRD, ICP-AES, SEM, HRTEM, 27Al NMR, H2-TPR, NH3-TPD, Py-IR, CO-TPD. Accordi...

three high-silica mordenite zeolites differing in sio440, ratio were prepared by direct synthesis without using any template. the products si02/a120, ratio is influenced by the starting gel composition. this ratio is increased upon ion-exchange with nh,cl and subsequent calcination to prepare protonic mordenite. the protonic mordenites with si02/a1203ra tios of 14.6,29.2 and 34.6 were character...

Charge separation and diffusion in type II multilayered structures of CdTe and CdSe nanocrystals with a polymer spacer are unambiguously proven by surface photovoltage spectroscopy. Holes accumulate in CdTe nanocrystal layers, and the electrons in CdSe nanocrystal layers. An increase of thickness of the polymer spacer strongly decreases the charge separation efficiency. Surface photovoltage tra...

In this study, Gd2O3 nanocrystal (Gd2O3-NC) memories with nanostructure tunneling layers are fabricated to examine their performance. A higher programming speed for Gd2O3-NC memories with nanostructure tunneling layers is obtained when compared with that of memories using a single tunneling layer. A longer data retention (< 15% charge loss after 104 s) is also observed. This is due to the incre...

It has been found that sodium hypochlorite enhanced the chemiluminescence (CL) of the CdTe nanocrystal (NC)-hydrogen peroxide system and that estrogens inhibited these CL signals in alkaline solution. CL spectra were used to investigate the mechanism of the CL enhancement. On the basis of the inhibition, a flow-injection CL method has been established for determination of three natural estrogens.

Cu-SAPO-34 (Cu-CZC) and Fe-mordenite (Fe-MOR) their mechanical mixture (50 : 50) have been exhaustively investigated by means of operando X-ray absorption spectroscopy under NH3-SCR conditions.

Framework-associated aluminum is demonstrated to facilitate a reversible switch between Lewis and Brønsted acidity in zeolites with the acid sites preferentially populating side-pockets case of mordenite.