An efficient N-heterocyclic carbene (NHC) catalyzed sulfenylation reaction of α,β-unsaturated aldehydes with N-(arylthio)phthalimide has been developed. A wide variety of α-thioenals can be obtained with good to excellent yields and excellent Z-configuration.

In this paper we construct a q-deformation of the Witt-Burnside ring of a profinite group over a commutative ring, where q ranges over the ring of integers. When q = 1, this coincides with the Witt-Burnside ring introduced by A. To achieve our goal we show that there exists a q-deformation of the necklace ring of a profinite group over a commutative ring. As in the classical case, i.e., the cas...

The following result is proved: Let R be a 2-torsion free semiprime ring, and let T : R → R be an additive mapping, related to a surjective homomorphism θ : R → R, such that 2T (x2) = T (x)θ(x) + θ(x)T (x) for all x ∈ R. Then T is both a left and a right θ-centralizer.

References http://genesdev.cshlp.org/content/16/12/1441.full.html#related-urls Article cited in: http://genesdev.cshlp.org/content/16/12/1441.full.html#ref-list-1 This article cites 38 articles, 22 of which can be accessed free at: service Email alerting click here top right corner of the article or Receive free email alerts when new articles cite this article sign up in the box at the Collecti...

In the light of increasing public mistrust, there is an urgent need to clarify the moral status of the medical profession and of the relationship of the clinician to his/her patients. In addressing this question, I first establish the coherence, within moral philosophy generally, of the concept of supererogation (the doing of more than one’s duty). I adopt the notion of an act of “unqualified” ...

In this paper we describe a system that uses patterns of eye blinks as a biometric. Each user chooses a personal blink pattern based on a song (for example “Jingle Bells”). To establish their identity, the user looks at the system’s camera and blinks to the cadence of their chosen song. Computer vision is used to detect the blinks and to compare the blinked cadence to a database of stored blink...

A daily diary study examined how chronic perceptions of a partner's regard affect how intimates interpret and respond to daily relationship stresses. Spouses each completed a diary for 21 days. Multilevel analyses revealed that people who felt less positively regarded read more into stressful events than did people who felt highly regarded, feeling more hurt on days after acute threats, such as...

Metris is a version of the Tetris game that uses a player’s musical response to control game performance. The game is driven by two factors: traditional game design and the player’s individual sense of music and sound. Metris uses tuning principles to determine relationships between pitch and the timbre of the sounds produced. These relationships are represented as bells synchronised with signi...