An efficient N-heterocyclic carbene (NHC) catalyzed sulfenylation reaction of α,β-unsaturated aldehydes with N-(arylthio)phthalimide has been developed. A wide variety of α-thioenals can be obtained with good to excellent yields and excellent Z-configuration.

In this paper we construct a q-deformation of the Witt-Burnside ring of a profinite group over a commutative ring, where q ranges over the ring of integers. When q = 1, this coincides with the Witt-Burnside ring introduced by A. To achieve our goal we show that there exists a q-deformation of the necklace ring of a profinite group over a commutative ring. As in the classical case, i.e., the cas...

The following result is proved: Let R be a 2-torsion free semiprime ring, and let T : R → R be an additive mapping, related to a surjective homomorphism θ : R → R, such that 2T (x2) = T (x)θ(x) + θ(x)T (x) for all x ∈ R. Then T is both a left and a right θ-centralizer.

In the light of increasing public mistrust, there is an urgent need to clarify the moral status of the medical profession and of the relationship of the clinician to his/her patients. In addressing this question, I first establish the coherence, within moral philosophy generally, of the concept of supererogation (the doing of more than one’s duty). I adopt the notion of an act of “unqualified” ...

In this experiment, we tested the hypothesis that adult-child differences in cue weighting are influenced by adult-child differences in knowledge of (a) the relative predictability of wordinitial vs. word-final consonants, and (b) of the relationship between predictability and acoustic salience/distinctiveness. We tested our hypothesis using synthetic speech continua with formant transitions va...