نتایج جستجو برای: optical rotation
تعداد نتایج: 333642 فیلتر نتایج به سال:
We consider the limitations due to noise (e.g., quantum projection noise and photon shot-noise) on the sensitivity of an idealized atomic magnetometer that utilizes spin squeezing induced by a continuous quantum nondemolition measurement. Such a magnetometer measures spin precession of N atomic spins by detecting optical rotation of far-detuned light. We show that for very short measurement tim...
We suggest the use of certain readily producible types of light to exert a force that points in opposite directions for the enantiomers of a chiral molecule and propose multiple devices based upon this novel manifestation of optical activity: in particular, our discriminatory chiral diffraction grating; a device that could be employed, for example, to measure the enantiomeric excess of a sample...
Four new prenylxanthones, emerixanthones A-D (1-4), together with six known analogues (5-10), were isolated from the culture of the deep-sea sediment derived fungus Emericella sp. SCSIO 05240, which was identified on the basis of morphology and ITS sequence analysis. The newstructures were determined by NMR (1H, 13C NMR, HSQC, HMBC, and 1H-1H COSY), MS, CD, and optical rotation analysis. The ab...
The ability to induce optical activity in nanoparticles and dynamically control its strength is of great practical importance due to potential applications in various areas, including biochemistry, toxicology, and pharmaceutical science. Here we propose a new method of creating optical activity in originally achiral quantum nanostructures based on the mixing of their energy states of different ...
Pasteur's chemical and crystallographic work is described. The article commences with a brief overview of related science (chemical structure, crystallography, optical activity) before and after 1848, the year of the discovery of molecular chirality and spontaneous resolution. Concerning this discovery, three separate and varying reports are described. These are: (i) the publications in the sci...
An approach to compute the polarizability tensor of magnetic nanoparticles having general ellipsoidal shape is presented. We find a surprisingly excellent quantitative agreement between calculated and experimental magneto-optical spectra measured in the polar Kerr configuration from nickel nanodisks of large size (exceeding 100 nm) with circular and elliptical shape. In spite of its approximati...
We discovered for the first time that light can twist metal to control the chirality of metal nanostructures (hereafter, chiral metal nanoneedles). The helicity of optical vortices is transferred to the constituent elements of the irradiated material (mostly melted material), resulting in the formation of chiral metal nanoneedles. The chirality of these nanoneedles could be controlled by just c...
Free radical polymerization of (+)-2,5-bis[4'-((S)-2-methylbutyloxy)phenyl]styrene yields a chiral polymer with memory of optical activity after the initial stereogenic center in the side group of the monomer is chemically removed.
Nonlinear magneto-optical rotation is investigated at high light powers where the rotation is significantly modified by ac Stark shifts. These shifts are shown to change the overall sign of rotation for closed F-->F+1 transitions compared to the low light power limit. The effect is demonstrated by measurements in rubidium and density matrix calculations. The results are important for applicatio...
We describe how the propagation of light through uniaxial crystals can be used as a versatile tool towards the spatial engineering of polarization and phase, thereby providing an all-optical technique for vectorial and scalar singular beam shaping in optics. Besides the prominent role played by the linear birefringence, the influence of circular birefringence (the optical activity) is discussed...
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