crosslinked poly(acrylic acid)s were prepared using two types of crosslinker by precipitation polymerization method in a binary organic solvent. n,n’-methylenebisacrylamide (mba) and polyethylene glycol dimethacrylate (pegdma-330) were used as low-molecular weight and long-chain crosslinkers, respectively. the effect of various types of crosslinkers on polymer characteristics (i.e., gel content...

Giant cell-like polymer vesicles, polymersomes, made from the diblock copolymer poly(ethylene oxide)-polybutadiene (PEO-PBD), have bilayer structures similar to the cell membrane but have superior and tunable properties for storage and stability. We have modified the terminal hydroxyl of the hydrophilic block with biotin-lysine (biocytin), a biologically derived group that imparts specific adhe...

All-polymer solar cells have shown great potential as flexible and portable power generators. These devices should offer good mechanical endurance with high power-conversion efficiency for viability in commercial applications. In this work, we develop highly efficient and mechanically robust all-polymer solar cells that are based on the PBDTTTPD polymer donor and the P(NDI2HD-T) polymer accepto...

We theoretically study phase transitions of a polymer threading through a pore imbedded in a membrane. We focus on the coupling between a partition of the polymer segments through the membrane and a coil-globule transition of the single polymer chain. Based on the Flory model for collapse transitions of a polymer chain, we calculate the fraction of polymer segments and the expansion factor of a...

It is widely appreciated that an attractive polymer-substrate interaction can slow relaxation in thin supported polymer films and polymer nanocomposites. Recent measurements and simulations on nancomposites have indicated that this slowing of polymer dynamics occurs more strongly near a highly attractive particle surface where a "bound" layer having a much lower mobility can form, strongly infl...

For ternary polymer-salt-water systems at low polymer concentration (0.5%, w/w), we have experimentally investigated the effect of polymer size on polymer diffusiophoresis (i.e., polymer migration induced by a salt concentration gradient) and salt osmotic diffusion (i.e., salt migration induced by a polymer concentration gradient). Specifically, Rayleigh interferometry was employed to measure t...

The authors investigated the polymer-mediated colloidal interactions in a good solvent wherein the particle size varies from that much smaller than the polymer radius of gyration up to macroscopic and the polymer concentration varies from that corresponding to a dilute solution to that close to a melt. At conditions directly accessible to molecular simulations, the theoretical predictions agree...

Knowledge of physiological and environmental factors is important for foragegrass production. Festuca ovina is a grass species adapted to Azerbaijan region climate,Iran. This species is a valuable source for forage production and soil conservation.Nitrogen (N), Phosphorus (P) and Potassium (K) are three most important plant nutrients.The aims of present study were to investigate the effects of ...