This paper reports on experimental results of aqueous heterophase polymerizations with monomers of quite different solubility in water ranging from the water-soluble 2-hydroxyethyl methacrylate to lauryl methacrylate with solubility in water of only about 10 mM. A calorimetric study revealed the strong influence of both the hydrophilicity of the monomer and the stirrer speed on the rate of poly...

A new facile cost-effective method for the oxidation of acetyl and carboethoxy derivatives of 3,4dihydropyrimidin-2(1H)-ones (DHPMs) by using potassium peroxydisulfate in water as solvent under microwave irradiation has been developed. Whereas the presence of the acetyl group instead of the carboethoxy group in position 5 decreases the rate of oxidation, the nature of the additional subtituent ...

Cobalt-containing metal oxides [perovskites (LaCoO(3), NdCoO(3), YCoO(3), La(0.7)Sr(0.3)CoO(3)), spinel (Co(3)O(4)) and wolframite (CoWO(4))] have been examined as catalysts for photocatalytic water oxidation with Na(2)S(2)O(8) and [Ru(bpy)(3)](2+) as an electron acceptor and a photosensitizer, respectively. Catalysts with the perovskite structure exhibited higher catalytic activity as compared...

background: tremendous amount of researches have investigated the issue of water photodisnfection. the aim of this research is to illustrate the influences of bacterial density, turbidity, exposure time and potassium persulfate (kps) dosage on the efficacy of associated solar disinfection (sodis) with kps for e. coli (atcc: 25922) eradication as an efficient and inexpensive process. methods: de...

a novel chemical detergent/disinfectant formulated based on persulfate salts, germicide p , is available for disinfection of surfaces and medical devices at the room temperature. because of the resistance of hospital-resident microorganisms, the antimicrobial activity of this compound is evaluated in the present study. the tests conducted with this disinfectant included bactericidal tests again...

With the increasing demand for novel process analytical technologies in recent years, Raman spectroscopy has been one of the powerful choices for in-situ reaction monitoring. In this paper, we discuss the use of in-situ Raman spectroscopy and the novel multivariate data analysis method, Band-Target Entropy Minimization (BTEM), to monitor the polymerization of methacrylamide using potassium pers...

The catalytic activity of four metal ions the fourth period table by D.I. Mendeleev in oxidation potassium iodide with ammonium persulfate. greatest increase reaction rate is observed presence copper sulfate, least cobalt and nickel salts

The advanced oxidation process based on persulfate has a broad application prospect in the remediation of organic pollutants. As an effective, low-cost and environmentally friendly material, nano-zero-valent iron (nZVI) can effectively activate (nZVI/PS) to generate strongly oxidizing sulfate radical for removing pollutants environment. In this review, we first clarify activation pathway nZVI a...

Erythrosine B is widely used for dyeing in various applications, especially in the food industry, despite its already proved toxicity and carcinogenicity. Therefore, the purpose of this study is to evaluate the efficiency of the synthesis process of US/S2O8-2 in removing erythrosine B dye from aqueous solution. In this experimental study, the removal of erythros...

MATERIALS 5x TBE electrophoresis buffer Polyacrylamide gels are poured and run in 0.5x or 1x TBE at low voltage (1-8 V/cm) to prevent denaturation of small fragments of DNA by Joulic heating. Other electrophoresis buffers such as 1x TAE (please see Agarose Gel Electrophoresis) can be used, but they are not as good as TBE. The gel must be run more slowly in 1x TAE, which does not provide as much...