Platinum(IV) can be determined spectrophotometrically with 5-chloro-2-hydroxythiobenzhydrazide on extraction into molten naphthalene from the aqueous phase with pH 2.2-6.0. Beer's law is obeyed in the concentration range 1.0-7.0 microg cm(-2) of Pt(IV) in 4-methyl-2-pentanone solution at 680 nm. The molar absorptivity and Sandell sensitivity are found to be 2.40 x 10(4) L mol(-1) cm(-1) and 8.0...

Screw-shaped implants made from rods of commercially pure titanium (grade 1) and titanium-aluminum-vanadium (grade 5) were machined, and the implant surface structures were numerically described before being placed in rabbit tibiae for healing periods of 1 months, 6 months, and 12 months. Quantitative comparisons of the removal torque (Ncm) necessary to loosen the implants from the bone bed wer...

Heterogeneous catalysis plays a key role in the manufacture of essential products in key areas of agriculture and pharmaceuticals, but also in the production of polymers and numerous essential materials. Our understanding of heterogeneous catalysts is advancing rapidly, especially by using the latest characterisation methods on these relatively complex effect materials. At the heart of these ca...

STUDY DESIGN An in vitro study examining factors produced by human mesenchymal stem cells on spine implant materials. OBJECTIVE The aim of this study was to examine whether the inflammatory microenvironment generated by cells on titanium-aluminum-vanadium (Ti-alloy, TiAlV) surfaces is affected by surface microtexture and whether it differs from that generated on poly-ether-ether-ketone (PEEK)...

The neutronics activities for SPPS included the determination of the blanket dimensions that provide tritium self-sufficiency, radiation damage to the structural materials, lifetime of the in-vessel components, radiation level at the superconducting magnets, and shielding requirements for magnet protection. The neutron wall loading varies in both poloidal and toroidal directions. For an average...

The oxovanadium(IV) complexes LVO and L'VO (L = dianion of 5,14-dihydro-6,8,15.17tetramethyldibenzo[b.i][l,4.8,ll]tetraazacyclotetradecine. H2L. and L' = dianion of 5.14-dihydro-6,15-dimethyl-8,17-diphenyldibenzo[b,i][l,4,8,1 l]tetraazacyclotetradecine, H2L') are redox active as indicated by cyclovoltammetric measurements and confirmed by preparative methods: Reversible oxidation to the corresp...