Radical-mediated thiodesulfonylation of the vinyl and (α-fluoro)vinyl sulfones, derived from aldehydes and ketones, with aryl thiols in organic or aqueous medium provided access to vinyl and (α-fluoro)vinyl sulfides. The vinyl sulfides were formed predominantly with E stereochemistry independent of the stereochemistry of the starting vinyl sulfones.

the aim of this work is to probe the influence of nanoclay and turmeric spends content on microcrystalline of vinyl ester hybrid nanocomposites. a series of vinyl ester hybrid nanocomposites have been fabricated with varying amounts of ts viz., 0, 2.5, 5, 7.5 and 10 % w/w along with 2% nanoclay. the microcrystalline parameters such as crystallite size and lattice strain of vinyl ester hybrid na...

Mesoporous α-Fe2O3 thin films with large area homogeneity demonstrate tremendous potential in multiple applications. In the present work, synthesis of morphology-controlled is realized polystyrene-block-poly(4-vinyl pyridine) (PS-b-P4VP) diblock copolymer assisted sol-gel chemistry. The solvent category (DMF and 1,4-dioxane) polymer-to-FeCl3 ratio used for solution preparation are systematicall...

We study the slowing down of polymer dynamics in canonical nanocomposites made strongly interacting mixtures poly-2-vinyl pyridine and silica nanoparticles (radius R = 7 ± 2 nm) by means low-field NMR relaxometry. demonstrate that this technique enables accurate quantification fraction immobilized (irreversibly adsorbed) on to filler surface, a manner complements data from broadband dielectric ...

in this research, a semi empirical approach has been suggested for calculating the activation energyof unimolecular thermal decomposition of vinyl ethers yielding saturated products. the calculationprocedure is based on the use of molecular mechanics (mm) methods. these methods which involvethe construction of the transition state for a molecule mainly consider the formation of a “hydrogenbridg...

poly vinyl alcohol/chitosan nanofibrous mat were prepared by electrospinning method with suitable pore sizes as potential matrices for soft tissue engineering. the designed scaffolds by electrospinning method evaluated by differentanalyses such morphological, mechanical, and cellular analysis.microscopic results showed diameters of poly vinyl alcohol/chitosan nanofibers were approximately 150 n...