objective(s): so far, extensive research has been conducted on the preparation and characterization of nano ceramics based on ca-si by sol- gel method and bioactivity was evaluated, but, a few researches have paid attention to the preparation of materials by mechanical activation (ma). the aim of this study was the preparation of akermanite nano powder by mechanical activation method and bioact...

Cu doped ZnS Nanoparticles in powder form were prepared by wet chemical route method by using thioglycerol as a capping agent. The prepared powder was characterized by using X-ray diffraction (XRD) analysis. The XRD studies indicated that most of the samples are having cubic phase. The absorption spectra, and photoluminescence behaviour of bulk ZnS, nano ZnS and Cu doped ZnS have been studied. ...

Nonlinear optical (NLO) crystals have come upon the materials science scene and are being studied by many research groups around the world. Most irradiation studies in the hydrogen bonded have been concentrated on the transient defects induced by ionizing radiation such as UV light, where the defects are closely related to the optical properties. Glycene Zinc Sulphate (GZS) Semi organic single ...

Calcium oxide was reported in the sol-gel-derived hydroxyapatite (HA) as an unavoidable major impurity. In this study phase purity of HA synthesized by sol-gel route was explored using precursors of calcium nitrate tetrahydrate and triethyl phosphate. Two different drying methods, the fast drying of as-prepared precursors and the slow drying of aged precursors were adopted as major processing v...

Silica and phosphate based bioactive glass nanoparticles (58SiO2-33CaO-9P2O5) with doping of neem (Azadirachta indica) leaf powder and silver nanoparticles were prepared and characterised. Bioactive glass nanoparticles were produced using sol-gel technique. In vitro bioactivity of the prepared samples was investigated using simulated body fluid. X-ray diffraction (XRD) pattern of prepared glass...

The study of the intercalation of organic compounds into clays, as in the preparat ion of pillared clays, is of great importance both from the theoretical point of view and for its applications in pharmacy, agriculture, clay characterization, catalysis, etc. (MacEwan and Wilson, 1980; Theng, 1974; Pinnavaia, 1983). At different temperatures, intercalated organic molecules, especially long-chain...

The metal-organic framework MOF-5 has attracted significant attention due to its ability to store large quantities of H2 by mass, up to 10 wt.% absolute at 70 bar and 77 K. On the other hand, sinceMOF-5 is typically obtained as a bulk powder, it exhibits a lowvolumetric density andpoor thermal conductivitydboth ofwhichareundesirable characteristics for ahydrogen storage material. Here we explor...

Alkali activated material has recently attracted great attention as an environmentally friendly building material. Generally, it exhibits higher mechanical properties and better durability when compared with Portland cement based materials. In this article, mixed alkali activated systems consisting of N-A-S-H and C-A-S-H hydrated gels were produced, using metakaolin as a dominated starting mate...

We present a modeling scheme to analyze cagelike silica mesoporous crystals based on in situ X-ray diffraction (XRD) data collected during gas adsorption-desorption (physisorption) processes. Nitrogen physisorption on a silica mesoporous crystal of SBA-16 was directly monitored by using synchrotron in situ powder XRD measurements conducted at SPring-8. SBA-16 is a well-ordered mesoporous silica...

mold powders used in the continuous casting of steel contain the harmful caf2 as a main substance developing toxic gases such as sif4 and hf at elevated temperatures. in this study, three samples of i1, i2 and i3, which contained gypsum free portland cement clinker with different percentages of fe2o3 (5.68, 6.83, 8.02 ) and f- (2.09, 1.06, 0), were prepared and their main characteristics were c...