The oxidative dehydrogenation (ODH) of propane to propylene by supported vanadia catalysts has received much attention in recent years, but different reactivity trends have been reported for this catalytic reaction system. In the present investigation, the origin of these differing trends are investigated with synthesis of supported V/SiO2, V/TiO2, and V/Al2O3 catalysts prepared with three diff...

The molecular structures, oxidation states, and reactivity of 3 and 6% CrO3/ZrO2 catalysts prepared by incipient wetness impregnation were examined under different conditions. The in situ Raman spectroscopic studies under dehydrated conditions reveal that the 3 and 6% CrO3/ZrO2 catalysts possess equal amounts of monochromate and polychromate species. Consequently, monolayer coverage on this ZrO...

the kinetics of catalyst deactivation and coke formation during dehydrogenation of propane over supported pt–based catalysts and, in particular, the effect of alkali metal promoters on catalyst activity and stability were studied. the analysis of propane conversion data showed that there is an optimum level of alkali metal promoter loading for both catalyst activity and stability.a model based ...

Three series of zeolite catalysts Co all-silica and Al-containing zeolites beta were prepared for use in the selective oxidative dehydrogenation propane to propylene. Two by a two-step postsynthesis method at pH = 2.5 3.0–9.0, respectively, which allows incorporation cobalt into SiBEA form isolated framework pseudo-tetrahedral Co(II) species. The ions vacant T-atom sites their reaction with sil...

The kinetics of catalyst deactivation and coke formation during dehydrogenation of propane over supported Pt–based catalysts and, in particular, the effect of alkali metal promoters on catalyst activity and stability were studied. The analysis of propane conversion data showed that there is an optimum level of alkali metal promoter loading for both catalyst activity and stability.A model ba...

Dehydrogenation processes play an important role in the petrochemical industry. High selectivity towards olefins is usually hindered by numerous side reactions a conventional cracking/pyrolysis technology. Herein, we show recent studies devoted to selective ethylene production via oxidative and non-oxidative reactions. This review summarizes progress that has been achieved with ethane conversio...