Radiation which has a quadrupole component of anisotropy, can get polarized by Thomson scattering from charged particles. In the cosmological context, the microwave background photons develop significant quadrupole anisotropy as they free stream away from the the epoch of standard recombi-nation. Reionization in the post recombination era can provide free electrons to Thomson scatter the incide...

The couplings between all amide fundamentals and their overtones and combination vibrational states are calculated. Combined with the level energies reported previously (Hayashi, T.; Zhuang, W.; Mukamel, S. J. Phys. Chem. A 2005, 109, 9747), we obtain a complete effective vibrational Hamiltonian for the entire amide system. Couplings between neighboring peptide units are obtained using the anha...

Evolution of quadrupole deformations in sd and pf shell nuclei with mass A= 18∼56 is studied by using deformed Skyrme Hartree-Fock (HF) model with pairing correlations. We point out that the quadrupole deformations of the nuclei with the isospin T=0 and T=1 show strong mass number dependence as a clear manifestation of dynamical evolution of deformation in nuclear many-body systems. The competi...

An effective exciton Hamiltonian for all amide bands is used to calculate the linear absorption and photon echo spectra of a 17 residue helical peptide (YKKKH17). The cross peak bandshapes are sensitive to the inter-band couplings. Fluctuations of the local amide frequencies of the all amide fundamental and their overtone and combination states are calculated using the multipole electric field ...