نتایج جستجو برای: reaction of oxygen atom with carbonyl sulfide
تعداد نتایج: 22204760 فیلتر نتایج به سال:
For the large-scale sustainable implementation of polymer electrolyte membrane fuel cells in vehicles, high-performance electrocatalysts with low platinum consumption are desirable for use as cathode material during the oxygen reduction reaction in fuel cells. Here we report a carbon black-supported cost-effective, efficient and durable platinum single-atom electrocatalyst with carbon monoxide/...
Bis-2-(5-phenylacetamido-1,3,4-thiadiazol-2-yl)ethyl sulfide (BPTES) is a selective inhibitor of glutaminase-1 (GLS1), consequently inhibiting glutaminolysis. BPTES known for its potent antitumor activity and plays significant role in senescent cell removal. In this study, we synthesized [11C-carbonyl]BPTES ([11C]BPTES) as positron emission tomography (PET) probe the first time assessed biodist...
the reaction of copper(ii) chloride and zinc(ii) chloride with n-(2-methylphenyl)-3-(1'-salicylaldehydene-2'-imine-ethane)-butanamide(h2l2a) or (mpsb), n-(2-methylphenyl)-3-(1'-(3'-methoxysalicylaldehydene-2'-imine-ethane)-butanamide (h2l2b) or (mpmsb) and n-(2-methylphenyl)-3-(1'-(2'-hydroxyacetylene-2'-imine-ethane)-butanamide (h2l2c) (mphb) leads to th...
The title Schiff base compound, C28H21Cl2N3O, was synthesized by the condensation of 1-(3,4-di-chloro-phen-yl)-3-methyl-4-(4-methyl-benzo-yl)-1H-pyrazol-5(4H)-one with 1-aminona-phthalene. The p-tolyl ring is normal to the pyrazole ring, with a dihedral angle of 88.02 (14)°, and inclined to the naphthalene ring system by 78.60 (12)°. The pyrazole ring is inclined to the naphthalene ring system ...
In the title compound, [Tb(CH(3)CN)(C(23)H(26)O(8))(H(2)O)(3)](ClO(4))(3), the Tb(3+) atom is eight-coordinated by one N atom of an acetonitrile molecule, three water O atoms and four ligand O atoms. The Tb(3+) atom is located on one side of the macrocycle and the carbonyl oxygen coordinated to the terbium [Tb1-O1= 2.210 (3) Å] is bent out of the xanthone plane by 0.514 (3) Å. The geometry arou...
Oxidative cleavage of poly(cis-1,4-isoprene) by rubber oxygenase RoxA purified from Xanthomonas sp. was investigated in the presence of different combinations of (16)O(2), (18)O(2), H(2)(16)O, and H(2)(18)O. 12-oxo-4,8-dimethyl-trideca-4,8-diene-1-al (ODTD; m/z 236) was the main cleavage product in the absence of (18)O-compounds. Incorporation of one (18)O atom in ODTD was found if the cleavage...
Density functional theory was used to study the effects of different types of oxygen-containing functional groups on the adsorption of oxygen molecules and single active oxygen atoms on carbonaceous materials. During gasification or combustion reactions of carbonaceous materials, oxygen-containing functional groups such as hydroxyl(-OH), carbonyl(-CO), quinone(-O), and carboxyl(-COOH) are often...
A nitroalkane-oxidizing enzyme was purified to homogeneity from Neurospora crassa. The enzyme is composed of two subunits; the molecular weight of each subunit is approximately 40,000. The enzyme catalyzes the oxidation of nitroalkanes to produce the corresponding carbonyl compounds. It acts on 2-nitropropane better than on nitroethane and 1-nitropropane, and anionic forms of nitroalkanes are m...
the complex of ce(iii), [ ce (phensc) (h 0) ] (c10 ) , was synthesized using the phensc, a hexadentate ligand,2,9-diformyl-1,lo- phenanthroline bis (semicarbazone), and characterized by x-ray diffraction. the cerium atom has an unusual coordination number of ten involving six donor atoms of the planar ligand in the equatorial plane and four oxygen atoms from four axial water molecules. the comp...
The induction period of the chemical reaction between Cu and S was visualized with STM, revealing a complex interplay between strain relief and reaction mechanism. Copper sulfide formation, monitored by high-resolution soft X-ray photoemission, started only after adsorption of ∼ 0.2 ML of S on a two-atom thick Cu layer supported by a Ru(0001) substrate. The pre-sulfide stages of sulfur interact...
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