global warming is one of the major concerns in environmental issues. its effects are being exposed faster than anticipated recently. it causes adverse ecological and socioeconomical effects. the 4th assessment report issued by the u. n.’s intergovernmental panel on climate change (ipcc) states that it is appropriate to define global warming was caused by greenhouse gases due to human activities...

Electrolysis with renewable electricity of water leads to hydrogen, which may be used directly as an energy carrier. However, storage of pure hydrogen is a technical challenge and requires a significant economic investment. The reduction of CO2 with hydrogen leads to hydrocarbons, which are for longer chains liquids at room temperature and easy to store. The electrochemical reduction of CO2 in ...

Reaction mechanisms for the catalytic hydrogenation of CO2 by faujasite-supported Ir4 clusters were studied by periodic DFT calculations. The reaction can proceed through two alternative paths. The thermodynamically favoured path results in the reduction of CO2 to CO, whereas the other, kinetically preferred channel involves CO2 hydrogenation to formic acid under water-free conditions. Both pat...

Carbon dioxide (CO2) emissions currently represent a major concern. Accordingly, the electrochemical reduction of CO2 is a reaction of major relevance and also of great challenges. Considering the redox potentials required for reducing CO2, multi-electron-transfer, multiproton reactions are the most viable pathways for driving CO2 reduction. [2] Nonetheless, catalysts must be employed to overco...