We report the preparation, characterization, and electrogenerated chemiluminescence (ECL) of rubrene nanoparticles (NPs) and 9,10-diphenylanthracene (DPA) nanorods. The organic NPs were prepared in an aqueous phase using a simple reprecipitation method, i.e., injecting a solution of the hydrocarbon in an organic solvent into water. The resulting NPs can be collected and redispersed to form stab...

Amorphous red-emitting materials involving solvatochromic small molecules have been processed by the reprecipitation method as non-doped nanospheres characterized by a remarkably low polydispersity. Their mean diameter could simply be tuned by the concentration of the organic solution giving rise to time-stable dispersion of 85-200 nm-sized nanoparticles. Time-resolved measurements performed on...

The chemical changes which occur during the process of carious destruction of enamel are complex due to a number of factors. First, substituted hydroxyapatite, the main component of dental enamel, can behave in a very complex manner during dissolution. This is due not only to its ability to accept substituent ions but also to the wide range of calcium phosphate species which can form following ...

Calcium phosphate (CaP) bioceramics are widely used in the field of bone regeneration, both in orthopedics and in dentistry, due to their good biocompatibility, osseointegration and osteoconduction. The aim of this article is to review the history, structure, properties and clinical applications of these materials, whether they are in the form of bone cements, paste, scaffolds, or coatings. Maj...

This study compared magnesium oxide and magnesium citrate with respect to in vitro solubility and in vivo gastrointestinal absorbability. The solubility of 25 mmol magnesium citrate and magnesium oxide was examined in vitro in solutions containing varying amounts of hydrochloric acid (0-24.2 mEq) in 300 ml distilled water intended to mimic achlorhydric to peak acid secretory states. Magnesium o...

Vascular smooth muscle cells (VSMC) in the rat mesenteric artery show specific immunofluorescent staining with antisera against purified human uterine myosin (ASMM) but not human platelet myosin (APM). However, in primary cultures produced by enzymatic dissociation of this vessel, VSMC stain specifically with both ASMM and APM within 5 h after plating and throughout growth to confluence (4-10 d...

The fossilization of organic remains and shell material by calcium phosphate minerals provides an illuminating, but time-bounded, window into Ediacaran–Cambrian animal evolution. For reasons that remain unknown, phosphatic fossil preservation declined signifi cantly through Cambrian Series 2. Here, we investigate the phosphorus (P) sources for phosphatic Cambrian carbonates, presenting sediment...

Large areas of abandoned tin-mining pools have found secondary uses which provide natural habitats for aquaculture activities where most freshwater fishes are bred. Soils from tin-mining areas are rich in uranium and thorium. A study has been conducted on the status of waters and aquatic habitats in disused tin-mining pools and at water intake points for public drinking water supply to assess t...

The primordial earth surface exposed minerals comprised mainly of carbonates, silicates and smaller amounts of phosphates. Weathering eventually led to the dissolution of the surface rock and the leaching of their components into the rivers, lakes and oceans. There, complex chemistry depending upon the temperature, pH, pressure, and atmospheric carbon dioxide content led to the reprecipitation ...

Intracellular signaling from the T cell receptor (TCR)zeta/CD3 complex is likely to be mediated by associated protein tyrosine kinases such as p59fyn(T), ZAP-70, and the CD4:p56lck and CD8:p56lck coreceptors. The nature of the signaling cascade initiated by these kinases, their specificities, and downstream targets remain to be elucidated. The TCR-zeta/CD3:p59fyn(T) complex has previously been ...