Novel SnO2/SiC hollow sphere nanochains were synthesized by topological morphology conversion of SnO2@C core-shell nanochains through a vapour-solid reaction. Evaluation of the SnO2/SiC HSNCs for the generation of hydrogen revealed that they exhibit excellent catalytic activity and durability.

A simple approach for the screening of oxygen evolution reaction (OER) electrocatalyst arrays by scanning electrochemical microscopy (SECM) in the substrate generation/tip collection (SG/TC) mode is described. The methodology is based on the application of a series (9−10 replicates) of double-potential steps to a catalytically active substrate electrode, which is switched between potentials whe...

Notes 1. Alternatively, grease and organic materials can be removed by heating platinum electrodes to redness in a flame. Do not touch electrode surfaces with your fingers after cleaning because grease and oil cause nonadherent deposits that can flake off during washing and weighing. 2. Chloride ion must be totally excluded from this determination because it attacks the platinum anode during el...

We have developed a simple solution process to synthesize tin oxide nanorods. The influence of precursors and the reaction temperature on the morphology of SnO2 is investigated. SnO2 nanorods are characterized by X-ray diffraction, transmission electron microscopy (TEM), scanning electron microscopy (SEM), and Raman spectroscopy. The as-grown SnO2 nanorods are uniform in size with a radius of 5...

Transition metal cobalt (Co) nanoparticle was designed as catalyst to promote the conversion reaction of Sn to SnO2 during the delithiation process which is deemed as an irreversible reaction. The designed nanocomposite, named as SnO2/Co3O4/reduced-graphene-oxide (rGO), was synthesized by a simple two-step method composed of hydrothermal (1(st) step) and solvothermal (2(nd) step) synthesis proc...

SnO2 nanowires have been prepared using the active carbon reaction with the fine SnO2 powder at low temperature (700 8C). These nanowires show rectangular cross-section, with their widths ranging from 10 to 50 nm. Branched nanowires with definite included angle are also observed in these products. The morphology and microstructure of the single crystalline SnO2 nanowires and the branched nanowi...

Chemical and magnetic states of iron doped tin oxide (SnO2) as a diluted magnetic semiconductor (DMS) at room temperature have been investigated using 57Fe Mössbauer spectrometry, XRD and magnetometery. The influence of the doping conditions of SnO2 with iron on the generation of oxygen defects was reviewed and discussed on the basis of ab initio calculations. The magnetic properties depended o...

In this report, we show for the first time that SnO2 nanowire based dye sensitized solar cells exhibit an open circuit voltage of 560mV, which is 200mV higher than that using SnO2 nanoparticle based cells. This is attributed to the more negative flat band potential of nanowires compared to the nanoparticles as determined by open circuit photo voltage measurements made at high light intensities....