We have synthesized a new metastable metal hydride with promising hydrogen storage properties. Body centered cubic (bcc) magnesium niobium hydride (Mg(0.75)Nb(0.25))H(2) possesses 4.5 wt% hydrogen gravimetric density, with 4 wt% being reversible. Volumetric hydrogen absorption measurements yield an enthalpy of hydride formation of -53 kJ mol(-1) H(2), which indicates a significant thermodynamic...

Neutrino reaction cross-sections, (ν µ , µ −), (ν e , e −), µ-capture and photoab-sorption rates on 12 C are computed within a large-basis shell-model framework , which included excitations up to 4¯ hω. When ground-state correlations are included with an open p-shell the predictions of the calculations are in reasonable agreement with most of the experimental results for these reactions. Woods-...

Agricultural and soil management practices have been reported to affect alachlor sorption–desorption and degradation rates. Though alachlor has been banned in the E.U. since 2006, it is still used in U.S. corn and soybean production. The objectives of this study were to: (a) assess differences in alachlor sorption due to tillage treatments (chisel plow and ridge tillage) on soils from three mid...

Sorption data were obtained with a Matawan soil and the following chromium (III) organic complexes: chromium (III) ascorbate, chromium (III) glutamate, chromium (III) histidine, chromium (III) mandelate, chromium (III) citrate, chromium (III) cysteine, chromium (III) serine, chromium (III) pyruvate and chromium (III) oxalate. The influence of pH (2-12), ionic strength (0.005-1 M) and concentrat...

Endosulfan (ES) is a micropollutant found in reverse osmosis concentrates from water reuse applications. Electrodialysis (ED) can remove and recover charged solutes from such concentrates. While polar compounds cannot normally be removed, their fate in ED is important as they can contribute to membrane fouling/poisoning and be released during cleaning. High adsorption of ES to ED membranes was ...

Rice straw charcoal, soot and fly ash (collectively termed "black carbon" or BC), which were found to widely exist in the environment and exhibit strong sorption of many organic compounds, were prepared for this study, and recorded as RC, SC, and FC, respectively. The characterization, sorption isotherm, and the effect of pH (from 3.0 to 9.0) on sorption capacity of each BC were investigated. I...

Although the major influence of black carbon (BC) on soil and sediment organic contaminant sorption is widely accepted, an understanding of the mechanisms and natural variation in pyrogenic carbon interaction with natural organic matter (NOM) is lacking. The sorption of a phenolic NOM monomer (catechol) and humic acids (HA) onto BC was examined using biochars made from oak, pine, and grass at 2...

Biochars have been proposed for remediation of metal-contaminated water due to their low cost, high surface area and high sorption capacity for metals. However, there is a lack of understanding over how feedstock material and pyrolysis conditions contribute to the metal sorption capacity of biochar. We produced biochars from 10 different organic materials by pyrolysing at 450 °C and a further 1...

The purpose of this work was to elucidate the repercussion of changing pH, incubation time and As(V) competition on fluoride (F-) sorption on forest and vineyard soil samples, pyritic, and granitic materials, as well as on the by-products pine sawdust, oak wood ash, mussel shell ash, fine and coarse mussel shell, and slate processing waste fines. To reach this end, the methodological approach w...

Structural parameters of raw and pre-treated viscose, modal and lyocell fibres were determined using X-ray diffraction, and compared with data obtained from iodine adsorption and tenacity measurements. A good correlation was found between iodine adsorption and structural changes. These structural parameters are correlated with surface thermodynamic parameters obtained by surface tension experim...