Abstract We prepared crystals of (C 6 H 5 C n 2 NH 3 ) PbBr 4 ( = 2, 3, 4), and evaluated their photoluminescence scintillation characteristics. According to the spectra under 340 nm excitation light, a peak at around 410 due free exciton emissions appeared in (2PEA), (3PPA) 8 (4PBA). The quantum efficiencies 2PEA, 3PPA 4PBA were 0.24, 0.01 0.04, respectively. In scintillation, sharp originatin...