The appearance of propargyl radicals as synthetic intermediates has increased in recent years from a structural curiosity to frequent occurrence. This minireview covers the synthetically relevant organic chemistry involving intermediacy radicals. review is organized by process employed radical generation, including H-atom abstraction, propargyl-X homolyses, addition enynes, reduction polar C=X ...

Plastic tarps are often used in soil fumigation to contain chemicals in the soil to increase efficacy and decrease emissions of fumigant vapors. This research has shown that plastic films have a significant capacity to sorb fumigant vapors and that the sorption is largely reversible. We tested three agricultural films (polyethylene and two highbarrier films) with four soil fumigants (methyl bro...

the microalgae, dunaliella salina was isolated from maharlu salt lake, south east of shiraz, iran. the isolated strain was identified by both morphological and physiological markers. the complete its region (its1 + its2) including the 5.8s rdna gene used as molecular marker confirmed our identification. growth and cell proliferation, total chlorophyll and carotenoid contents were determined in ...

The title compound, C(16)H(13)NOS, was prepared by alkyl-ation of 1-(benzothia-zol-2-yl)propan-2-one with propargyl bromide. The asymmetric unit contains two mol-ecules that are crystallographically independent but linked to each other by non-classical C-H⋯O hydrogen bonds, building up a dimeric substructure. The benzothia-zole rings are essentially planar with maximum deviations of 0.005 (1) a...

Ruthenium-catalyzed simple, cascade and one-pot synthesis of cinnoline-fused diones has been carried out by the C-H activation of phthalazinones/pyridazinones accomplished by the unusual deoxygenation of propargyl alcohols. The bond selectivity is accredited to the traceless directing nature of the hydroxyl group of propargyl alcohol. A sequential C-H activation, insertion and deoxy-oxidative a...

Soil fumigation in greenhouses or agricultural fields often includes tarping the soil surface with polyethylene (PE) films to contain the fumigant in the soil and reduce emissions to the atmosphere. Previous research has demonstrated that PE films are permeable to methyl bromide and other fumigant compounds. In these experiments, the effect of temperature, fumigant mixtures, condensed water, an...

Synthesis and structural characterization of 1,4,2-oxazaphosphepines is described. The 1,4,2-oxazaphosphepines were obtained from reaction of chiral 1,3-benzoxazines with dichlorophenylphosphine or triethyl phosphite. The configuration of some of these compounds was stablished by X-ray analysis.

DESCRIPTION The active ingredient in ATROVENT (ipratropium bromide) Inhalation Aerosol is ipratropium bromide. It is an anticholinergic bronchodilator chemically described as 8azoniabicyclo[3.2.1]-octane, 3-(3-hydroxy-1-oxo-2-phenylpropoxy)-8-methyl-8-(1methylethyl)-, bromide, monohydrate (endo,syn)-,(±): a synthetic quaternary ammonium compound chemically related to atropine. The structural fo...