L-Tartrate ions can endure hydrothermal conditions up to 160 degrees C to form the robust, enantiopure open-framework coordination polymers [Ln2(L-TAR)3(H2O)2]3H2O, 1; the addition of succinate results in formation of the related [Ln2(L-TAR)2(SUC)(H2O)2]5.5H2O, with larger channels than , whereas racemic D/L-tartrate gives the more condensed [Ln2(D/L-TAR)3(H2O)2], . TAR = [C4H4O6]2-.

Human immunodeficiency virus, type 1 (HIV-1), Tat activates elongation of RNA polymerase II transcription at the HIV-1 promoter through interaction with the cyclin T1 (CycT1) subunit of the positive transcription elongation factor complex, P-TEFb. Binding of Tat to CycT1 induces cooperative binding of the P-TEFb complex onto nascent HIV-1 TAR RNA. Here the specific interaction between Tat prote...

This is a review of the literature available on data for the EROI (prior to this special issue) of the following 12 sources of fuel/energy: oil and natural gas, coal, tar sands, shale oil, nuclear, wind, solar, hydropower, geothermal, wave/tidal and corn ethanol. Unfortunately, we found that few studies have been undertaken since the 1980s, and such as have been done are often marked more by ad...

The efficient, economical conversion of fossil feedstocks requires improvements in the controlof the individual reactions, better management of hydrogen, and more selective removal ofheteroatoms. The challenges are increasing as feedstocks such as heavy oils, tar sands, shale,and coal become heavier. Progress requires the detailed understanding of the compositions ofthe feedstoc...

The AOC Granite 7-32-89-10 hole, drilled to search for oil in the Precambrian basement below the Alberta bituminous (tar) sands near Fort McMurray, Canada, penetrates layered biotite-hypersthene quartz diorite-gabbro sills that occur between 543 and 2363.3 meters depth. Three episodes of fracturing and cataclasis affected these sills. The first allowed Kand Si-metasomatism to change many parts ...

[1] The transport and deposition behavior of pathogenic Escherichia coli O157:H7 was studied under unfavorable electrostatic conditions in saturated quartz sands of various sizes (710, 360, 240, and 150 mm) and at several flow rates. At a given velocity, column effluent breakthrough values for E. coli tended to decrease in magnitude, and concentration curves became more asymmetric with decreasi...

Short basic peptides from the HIV Tat protein bind specifically to a bulge region in TAR RNA, with a single arginine residue providing the only sequence-specific contact. The free amino acid arginine also binds specifically to TAR. Previous circular dichroism (CD) experiments suggested that peptide binding induces a conformational change in TAR. Here we confirm this observation using single arg...

A series of neomycin dimers have been synthesized using "click chemistry" with varying functionality and length in the linker region to target the human immunodeficiency virus type 1 (HIV-1) TAR RNA region of the HIV virus. The TAR (Trans-Activation Responsive) RNA region, a 59 bp stem-loop structure located at the 5'-end of all nascent viral transcripts, interacts with its target, a key regula...

Qs Sand Wind-blown sand blankets a number of areas in the western part of the quadrangle. These well-sorted, mediumto fine-grained quartzose sands are commonly deposited on the east to northeast sides of hills but may extend across some flat areas. The sands are uncemented and loose but most are well stabilized by vegetation, locally including trees. The sands are usually white to tan but local...