in this paper, macrocyclic cobalt(ii) complexes [col1](no3)2.4h2o (1) and [col2](no3)2.2h2o (2) have been synthesized from the reaction of dialdehydes 1,2-bis(2-formylphenyl)ethane and 1,3-bis(2-formylphenyl)propane, co(no3)2.6h2o and 1,2-cyclohexanediamine with molar ration 1:1:1 in methanole and characterized by elemental analyses and ft-ir spectroscopy. then used as precursors for preparatio...

in the current study, synthesis and characterization of a new nano-structured zirconium(iv)-minoxidil complex (1), where minoxidil, (c9h15n5o; 6-(1-piperidinyl)-2,4-pyrimidinediamine 3-oxide), have been investigated in two different solvents. the compound 1 has been synthesized by sonochemical method in the presence of methanol and monoethylene glycol (meg) as solvents and characterized by scan...

To investigate the reaction kinetics of the solid-state degradation process of enalapril maleate, a Fourier transform infrared microspectroscope equipped with thermal analyzer (thermal FT-IR microscopic system) was used. The isothermal stability study was conducted at 120-130 degrees C for 1-2 h and changes in the three-dimensional plots of the IR spectra of enalapril maleate with respect to he...

In Brazil, due to its availability, sugar cane bagasse has a high potential for power generation. The knowledge of ignition behavior, as well as the knowledge of the chemical kinetics, in of fuels combustion process is important features in boilers projects and in the stability of the combustion process control. The aim of this study is to investigate the thermal behavior of sugar cane bagasse,...

We introduce and discuss the Homotopy perturbation method, the Adomian decomposition method and the variational iteration method for solving the stefan problem with kinetics. Then, we give an example of the stefan problem with  kinetics and solve it by these methods.