Solar direct, indirect and hybrid thermochemical processes are presented for the generation of hydrogen and compared to alternate solar hydrogen processes. A hybrid solar thermal/electrochemical process combines efficient photovoltaics and concentrated excess sub-bandgap heat into highly efficient elevated temperature solar electrolysis of water and generation of H2 fuel utilizing the thermodyn...

Low thermal conductivity and high thermal stability are desirable for the materials due to their characteristic roles in ablation resistance applications (e.g., reentry parts and renewable rocket nozzles) [1]. Ablation is defined as an erosive phenomenon with a removal of material by a combination of thermomechanical, thermochemical and thermophysical factors due to the high temperature, pressu...

As a follow-up on a study of a family of boron-oxygen-nitrogen compounds composed of two datively bonded B-O-N backbones, we investigate a similar series of compounds that have similar fragments but are covalently bonded. B3LYP/6-31G(d,p) quantum mechanical calculations have been performed to determine the minimum-energy geometries, vibrational frequencies, and thermochemical properties of the ...

Density functional theory (DFT) has become the method of choice for many applications of quantum mechanics to the study of the electronic properties of molecules and solids. Despite the enormous progress in improving the functionals, the current generation is inadequate for many important applications. As part of the quest of finding better functionals, we consider in this paper the Perdew-Burk...

As one of the most environmentally friendly and cost-effective method, anaerobic digestion (AD) has been widely studied and developed as a conventional technology to degrade biodegradable materials and produce biogas simultaneously. Various substrate sources are used in this process such as organic fraction of municipal solid waste (MSW), waste activated sludge (WAS), animal manures, agro-indus...

•Large entropy of reduction and intermediate enthalpy reduction•pO2-dependent reversible structural transition: orthorhombic ? tetragonal cubic•Outstanding H2 yield 10 mL g?1 upon at 1,350°C a cycle time 1.5 h•H2 production rate limited by gas-phase mass transport rather than material kinetics A global transition away from fossil fuel energy to sustainable sources, in particular solar energy, r...

An unsymmetrical star-shaped pi-system (1) with an isotruxene core and three fluorene arms has been synthesized, and its photophysical, electrochemical, and thermochemical properties have been investigated and compared with the corresponding symmetrical truxene derivatives 2a-d (Kanibolotsky, A. L.; Berridge, R.; Skabara, P. J.; Perepichka, I. F.; Bradley, D. D. C.; Koeberg, M. J. Am. Chem. Soc...

Various methods of water-splitting with use of solar energy are reviewed and compared to each other. Direct thermal method has the highest efficiency, but the difficulty is the heat-resisting materials. Thermochemical method is pro­ mising if the corrosion-resisting materi­ als are found. Electrolytic method is tra­ ditional, but the hybrid system combined with thermochemical and/or photochemic...