نتایج جستجو برای: thermodynamic behavior
تعداد نتایج: 656729 فیلتر نتایج به سال:
We study the thermodynamic behavior of branched polymers. We first study random walks in order to clarify the thermodynamic relation between the canonical ensemble and the grand canonical ensemble. We then show that correlation functions for branched polymers are given by those for straight phi(3) theory with a single mass insertion, not those for the straight phi(3) theory themselves. In parti...
ESR studies on spin-labeled amorphous RNase A as a function of varying concentrations of sorbed H2O and D2O will be presented. A relaxation analysis of saturation transfer (ST-)ESR spectra of 14N(1H) nitroxide spin-label molecules essentially fixed at amino acid residue His-105 will be given. A characteristic correlation has been observed between the microdynamic behavior--expressed by the rota...
General anesthetics are known to cause depression of the freezing point of transitions in biomembranes. This is a consequence of ideal mixing of the anesthetic drugs in the membrane fluid phase and exclusion from the solid phase. Such a generic law provides physical justification of the famous Meyer-Overton rule. We show here that general anesthetics, barbiturates, and local anesthetics all dis...
(1) In the previous lectures the behavior of the macroscopic thermodynamic functions of systems in equilibrium near critical points has been discussed. Notations for the various exponents describing the critical singularities have been introduced and the connections between them have been described [l]. In this talk we enter the microscopic domain by studying the correlation fun...
We have performed a combined experimental and theoretical study of the thermodynamic properties of semifluorinated alkanes. In particular, the liquid density of perfluorohexylhexane (F6H6) and perfluorohexyloctane (F6H8) has been measured as a function of temperature from 273.15 to 353.15 K and at four temperatures as a function of pressure up to 600 bar. The results were interpreted using the ...
We review various simplified models that have been advanced to describe layering (complexion) transitions at grain boundaries in multicomponent solids. In particular, we first outline lattice-gas, off-lattice atomistic and thermodynamic models that have been employed to investigate phase-like behavior at segregated grain boundaries. The results of these investigations are summarized in the form...
We provide a complete thermodynamic solution of a 1D hopping model in the presence of a random potential by obtaining the density of states. Since the partition function is related to the density of states by a Laplace transform, the density of states determines completely the thermodynamic behavior of the system. We have also shown that the transfer matrix technique, or the so-called dynamic p...
In the present paper are analysing the conditions for the validity of the Tsallis Statistics. The same have been doing following the analogy with the traditional case: starting from the microcanonical description of the systems and analysing the scaling properties of the fundamental macroscopic observables in the Thermodynamic Limit. It is shown that the Generalized Legendre Formalism in the Ts...
In the present paper are analyzed the conditions for the validity of the Tsallis Statistics. The same have been done following the analogy with the traditional case: starting from the microcanonical description of the systems and analysing the scaling properties of the fundamental macroscopic observables in the Thermodynamic Limit. It is shown that the Generalized Legendre Formalism in the Tsal...
We solve the spin-1 quantum Ising model with single-ion anisotropy by mapping it onto a series of segmented spin-1/2 transverse Ising chains, separated by the S(z)=0 states called holes. A recursion formula is derived for the partition function to simplify the summation of hole configurations. This allows the thermodynamic quantities of this model to be rigorously determined in the thermodynami...
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