A system's equilibrium variance can be analyzed to probe its underlying dynamics at higher resolution. Here, using single-molecule atomic-force microscope techniques, we show how the variance in the length of a single dextran molecule can be used to establish thermodynamic equilibrium and to detect conformational changes not directly observable with other methods. Dextran is comprised of a chai...

Solubility of hydrocarbons in water is important due to ecological concerns and new restrictions on the existence of organic pollutants in water streams. Also, the creation of a thermodynamic model has required an advanced study of the phase equilibrium between water (as a basis for the widest spread muds and amines) and gas hydrocarbon phases in wide temperature and pressure ranges. Therefore,...

In this work the spectrally resolved, multigroup and mean radiative opacities of carbon plasmas are calculated for a wide range of plasma conditions which cover situations where corona, local thermodynamic and non-local thermodynamic equilibrium regimes are found. An analysis of the influence of the thermodynamic regime on these magnitudes is also carried out by means of comparisons of the resu...

We present a review of recent work on the statistical mechanics of non equilibrium processes based on the analysis of large deviations properties of microscopic systems. Stochastic lattice gases are non trivial models of such phenomena and can be studied rigorously providing a source of challenging mathematical problems. In this way, some principles of wide validity have been obtained leading t...

the main goal of this study is to investigate the capability of zeolites a and p synthesized from iranian natural clinoptilolite for uranium uptak. the removal of uranium(vi) from aqueous solution via ion exchange by zeolites in a single component system with various contact times,  temperatures and initial concentrations of uranium(vi) was investigated. the experimental results were fitted to ...

At temperatures moderately below their glass transition temperature, the properties of many glass-forming materials can evolve slowly with time in a process known as physical aging whereby the thermodynamic, mechanical, and dynamic properties all drift towards their equilibrium values. In this work, we study the evolution of the thermodynamic and dynamic properties during physical aging for a m...

We discuss the conditions for which the non-equilibrium work relation is valid by means of thermodynamic and microscopic arguments.

the second law of thermodynamic (entropy principle) is of special theo-philosophical importance. it seems that this law, which is renowned as “the death of software design” and despite the order in the world, is like an incompatible universal. this article examines the concept of entropy in the three temperature, statistic, and information applications and addresses the contradiction of the sec...

a numerical framework has been proposed to model the interacting effects of mixture non-ideality and mass transfer on hydrodynamics of a multiphase system using cfd methods.mass transfer during condensation and vaporization is modeled by chemical potential at the liquid-vapor interface. species mass transfers are related to the diffusion at the interface which in turn is related to the concentr...

finding a representative fluid in a hydrocarbon reservoir is crucial for integrated reservoir management. in this study, a systematic approach for screening and selecting consistent fluid samples in a reservoir was developed. the model integrated quality control (qc) of well conditioning before sampling, qc of pvt data, thermodynamic modeling and compositional gradient within a reservoir. well ...