This interdisciplinary project investigates the performance of nanoscale metalinsulator-semiconductor (MIS) contact structures that electrically couple optimized catalysts to high quality semiconductor absorbers in photoelectrochemical (PEC) cells, while chemically protecting the absorbers from oxidation during solar-driven water splitting. In the 2013-14 funding period, we completed and publis...

TiO2/SiO2 composites were synthesized via a simple sol gel method by surface reduction of Ti4+ ions to Ti3+ using titanium isopropoxide as TiO2 precursor and rice husks (RHA) SiO2 source. The silica content calcination temperature the materials evaluated. Thermal, crystallographic physicochemical aspects suggest that biogenic (SiO2) can improve thermal stability anatase phase TiO2, when reaches...

The catalytic hydrogenation of lactic acid to 1,2-propanediol with supported Ru catalysts in water was investigated. The influence of catalyst support (activated carbon, γ-Al2O3, SiO2, TiO2, and CeO2) and promoters (Pd, Au, Mo, Re, Sn) on the catalytic performance was evaluated. Catalytic tests revealed that TiO2 yields the best Ru catalysts. With a monometallic Ru/TiO2 catalyst, a 1,2-propaned...

in this research we have developed a treatment method for textile wastewater by tio2/sio2-based magnetic nanocomposite. textile wastewater includes a large variety of dyes and chemicals and needs treatments. this manuscript presents a facile method for removing dyes from the textile wastewater by using tio2/sio2-based nanocomposite (fe3o4@sio2/tio2) under uv irradiation. this magnetic nanocompo...

Cr2O3 and Cr2O3–SiO2-TiO2 coatings are deposited on P265GH steel using atmospheric plasma spraying. The influence of silicon oxide—titanium oxide addition the surface morphology coatings, phase composition tribological properties under non-lubricated sliding conditions investigated. SiO2-TiO2 led to formation a more uniform reduce roughness coatings. X-ray diffraction (XRD) studies indicated th...

PURPOSE In our previous study, Ag+-loaded TiO2 and Ag+-loaded SiO2 coatings for tracheal intubation were prepared to prevent ventilator-associated pneumonia (VAP), but the antimicrobial targets and the underlying mechanisms of TiO2 and Ag-TiO2 (Ag+) are still unclear. We attempted to elucidate the antimicrobial activity and potential mechanisms against Staphylococcus aureus. METHODOLOGY The s...

Hydrophobic Y-zeolite (SiO2/Al2O3 = 810) and TiO2 composite photocatalysts were designed by using two different types of TiO2 precursors, i.e., titanium ammonium oxalate and ammonium hexafluorotitanate. The porous structure, surface property and state of TiO2 were investigated by various characterization techniques. By using an ammonium hexafluorotitanate as a precursor, hydrophobic modificatio...

TiO2-SiO2-Ag composites are fabricated by depositing TiO2 films on silica substrates embedded with Ag nanoparticles. Enhancement of light absorption of the nanostructural composites is observed. The light absorption enhancement of the synthesized structure in comparison to TiO2 originated from the near-field enhancement caused by the plasmonic effect of Ag nanoparticles, which can be demonstrat...

TiO2 photo catalyst was prepared in presence of nano SiO2 and Hydroxy Propyl Cellulose (HPC) by sol gel method with Titanium Tetra IsoproPoxide (TTIP) as titanium precursor. Additional effect of HPC in preparation of nano catalyst, and photo catalyst properties measured and characterized by FT-IR, FT-Raman and SEM. The catalyst size and structural properties of the film were determined by .-Ray...