From the reactions between M2(T i PB)4 compounds and meta and para - vinylbenzoic acids (2 equiv) in toluene at room temperature the compounds trans-M2(T i PB)2L2, where L = m-vinylbenzoate 1A (M = Mo) and 1B (M = W) and T i PB = 2,4,6-triisopropylbenzoate, and where L = p-vinylbenzoate 2A (M = Mo) and 2B (M = W) have been isolated. Compounds 1A and 2A have been shown to undergo Heck carbon-car...

Alkali metal reduction of tungsten tetrachloride in the presence of excess trimethylphosphite and ethylene affords moderate yields of trans-tetrakis(trimethylphosphite)tungsten bis(ethylene). This easily prepared species bearing inexpensive ancillary ligands promotes the oxidative coupling of carbon dioxide and ethylene at ambient temperature to produce two isomeric tetrakis(trimethylphosphite)...

Morphological and chemical characteristics were determined for airborne tungsten particles in Fallon, Nevada, a town that is distinguishable environmentally by elevated airborne tungsten and cobalt. From samples of airborne dust collected previously at six different places in Fallon, tungsten-rich dust particles were isolated and analyzed with automated electron microprobe and wavelength-disper...

The Ni-based coatings with different content of spherical tungsten carbide were deposited by plasma transfer arc welding (PTAW) method on 304 austenitic stainless steel sheets in this study. The microstructure and wear property of spherical tungsten carbide particle reinforced composite coatings were investigated by means of optical microscope, scanning electron microscope (SEM), X-ray diffract...

The high average power laser (HAPL) program goal is to develop a laser inertial fusion reactor using a solid first wall (FW). The FW of the inertial fusion energy (IFE) chamber is exposed to high energy photon, particle, and neutron fluxes at frequency of several Hz. The feasibility of using a micro-engineered refractory metals, such as tungsten foam as a solid FW armor is investigated. Refract...

The hydrogen evolution reaction (HER) is one of the most promising methods obtaining high-purity hydrogen. However, high cost and limited resources materials with low cathodic overvoltage values, such as platinum group metals, are main obstacles to use HER for on an industrial scale. Therefore, it necessary develop new alternative their production. One catalysts based refractory in particular t...