Herein we describe the development of a reactor for continuous flow generation and use dimethyldioxirane (DMDO) its application to low-level epoxidation unsaturated polymers.

[1] Most analytical and numerical models developed to analyze pumping test data focus on saturated flow below the water table. Traditionally the soil above the initial water table prior to pumping has been thought to have little influence on the test results and has usually been ignored. It is hypothesized that, if the unsaturated zone is capped by low-permeability soil, airflow in the unsatura...

[1] It is commonly assumed in stochastic solute (advective) transport models that either the velocity field is stationary (statistically homogeneous) or the mean flow is unidirectional. In this study, using a Lagrangian approach, we develop a general stochastic model for transport in variably saturated flow in randomly heterogeneous porous media. The mean flow in the model is multidirectional, ...

The current concept for high-level radioactive waste disposal at Yucca Mountain is for the waste to be placed in underground tunnels (or drifts) in the middle of a thick unsaturated zone. Flow modeling and field testing have shown that not all flow encountering a drift will seep into the drift. The underlying reason for the diversion of unsaturated flow around a drift is that capillary forces i...

A two-dimensional numerical model based on smoothed particle hydrodynamics (SPH) was used to simulate unsaturated (multiphase) flow through fracture junctions. A combination of standard SPH equations with pairwise fluid-fluid and fluid-solid particle-particle interactions allowed surface tension and three-phase contact dynamics to be simulated. The model was validated by calculating the surface...

Unsaturated flow of soils in unsaturated soils is an important problem in geotechnical and geo-environmental engineering. Richards’ equation is often used to model this phenomenon in porous media. Obtaining appropriate solution to this equation therefore provides better means to studying the infiltration into unsaturated soils. Available 5 methods for the solution of Richards’ equation mostly f...