Non-flouro copolymers containing a hydrophobic alkyl acrylate monomer (butyl acrylate/2-ethylhexyl acrylate/ lauryl acrylate) and a reactive monomer (maleic anhydride) have been synthesized using emulsion polymerization technique. The copolymer emulsions have been applied on to cotton fabric by a pad-dry-cure process and the water repellency of the fabrics before and after vigorous washes compa...

Polymer-dispersed liquid crystal (PDLC) films were prepared by the ultraviolet-light-induced polymerization of photopolymerizable monomers in nematic liquid crystal/chiral dopant/thiol-acrylate reaction monomer composites. The effects of the chiral dopant and crosslinking agents on the electro-optical properties of the PDLC films were systematically investigate. While added the chiral dopant S8...

Poly(acrylic acid-co-allyl acrylate) statistical copolymers were synthesized in a controlled manner in two steps: first tert.butyl acrylate and allyl acrylate were polymerized via atom transfer radical polymerization (ATRP) and afterwords the tert.butyl protective groups were removed via hydrolysis. Samples of self cleaning glass (SCG) were coated with thin films of poly(acrylic acid-co-allyl a...

Urethanes have marked physiological activity in plants and animals. Lefevre (1939) found that phenyl urethane affects wheat germination, and subsequently Templeman and Sexton (1946) showed that a variety of urethanes suppress the germination of wheat and oats without affecting charlock. The most active urethanes (for example, isopropylphenylcarbamate;ethylphenylcarbamate) are effective at a con...

The cochlea converts sound vibration into electrical impulses and amplifies the low-level sound signal. Urethane, a widely used anesthetic in animal research, has been shown to reduce the neural responses to auditory stimuli. However, the effects of urethane on cochlea, especially on the function of outer hair cells, remain largely unknown. In the present study, we compared the cochlear microph...

High solids content film-forming poly[styrene-co-(n-butyl acrylate)] [poly(Sty-co-BuA)] latexes armored with Laponite clay platelets have been synthesized by soap-free emulsion copolymerization of styrene and n-butyl acrylate. The polymerizations were performed in batch in the presence of Laponite and a methyl ether acrylate-terminated poly(ethylene glycol) macromonomer in order to promote poly...

Two kinds of fluorinated polymers were synthesized: an acrylate polymer having a fluorinated triethylene glycol as a pendant group (2a) and a fluoroalkyl acrylate polymer (2b). The contact angle of these fluorinated polymers against water, non-fluorinated alcohols and fluorinated alcohols were evaluated. As compared with the fluoroalkyl polymer (2b), fluoroethylene glycol polymer (2a) showed sm...

The acrylate radicals produced by addition of aminoalkyl radicals to an acrylate unit were directly observed by transient absorption spectroscopy. These acrylate radicals are characterized by a strong absorption in the visible region of the spectrum allowing an easy study of their chemical reactivity. Therefore, a new method for the determination of both the addition and recombination rate cons...