We have developed a convenient and effective XRF analysis procedure for trace amount of K, Ca, V, Mn, Fe, Ni, Cu, Zn, Cd, and Pb in environmental waters by using a preconcentration using the natural polymer (agar). The thin agar film was prepared by drying a homogeneous agar gel after mixing the aqueous sample solution with the agar powder. XRF analysis of the preconcentrated thin agar films co...

The Kosa (yellow sand) aerosol affects the global environment as well as human health because it migrates from the interior of China to other areas, absorbing various atmospheric elements. Investigation into individual Kosa aerosol particles, which are submicroscopic to several tens of micrometers in diameter, is required to resolving the issue. We installed a scanning electron microscope (SEM)...

Applications of X-ray fluorescence (XRF) analysis with a pyroelectric X-ray generator are presented. Glass and ceramics were analyzed with this novel X-ray generator to examine its capability for analyzing nonmetallic inorganic material. Although the power of X-ray output was a few orders of magnitude lower than conventional X-ray tubes, many elements such as Si, K, Ca, Ti, Cr, Fe, Zn, Sr, Ba, ...

We report on a radically new elemental imaging approach for the analysis of biological model organisms and single cells in their natural, in vivo state. The methodology combines optical tweezers (OT) technology for non-contact, laser-based sample manipulation with synchrotron radiation confocal X-ray fluorescence (XRF) microimaging for the first time. The main objective of this work is to estab...

K. Tsuji, K. Tsutsumimoto, K. Nakano, K. Tanaka, A. Okhrimovskyy, Y. Konishi, and X. Ding Department of Applied Chemistry; Graduate School of Engineering; Osaka City University; 3-3-138 Sugimoto; Sumiyoshi-ku, Osaka 558-8585; Japan Telephone/Fax: +81-(0)6-6605-3080; E-mail: [email protected] 2) JST-PREST; 4-1-8 Honcho Kawaguchi, Saitama; Japan Institute of Low Energy Nuclear Physi...

Raman spectroscopy and X-ray fluorescence (XRF) analysis are commonly applied to archaeological objects as a fast and nondestructive way to characterize the materials. Here, micro-Raman spectroscopy and chemometrics on handheld XRF results were used to completely characterize beads found during archaeological excavations in the Congo. Metallic objects, organogenic materials, and glass beads wer...

Two XRF specimen preparation methods were investigated for quantifying gallium in plutonium metal. Gallium in plutonium was chosen here as an example for demonstrating the efficacy of wavelength dispersive XRF for quantifying radioactive materials. The steps necessary to handle such materials safely will also be discussed. Quantification of plutonium samples by a wellestablished aqueous specime...

New plastic certified reference materials (CRMs) with Pb, Cd and Cr for XRF analysis have been developed in cooperation with the Japan Society for Analytical Chemistry. These CRMs (named as JSAC 0611 – 0615) were prepared by casting polyester including a toluene solution of organometallic compounds as a standard. The disk was removed from the glass plate after 12 h of hardening at room temperat...

Analysis of rodent brains with X-ray fluorescence (XRF) microscopy combined with immunohistochemistry allowed us to demonstrate that local Cu concentrations are thousands of times higher in the glia of the subventricular zone (SVZ) than in other cells. Using XRF microscopy with subcellular resolution and intracellular X-ray absorption spectroscopy we determined the copper (I) oxidation state an...

Given the paucity of empirical constraints, the nature of the newly-recognized phenomena called X-Ray Flashes (XRFs) has been an open question. However, with the recent detections of radio and X-ray afterglow it is finally possible to study the large-and small-scale environments of XRFs. We present Chandra, Hubble Space Telescope (HST), and Keck observations of the fields of XRFs 011030 and 020...