Metal ions can significantly expand the scope of macromolecular catalysis. For catalysts composed of nucleic acids (DNA or RNA), metal ions are typically required for both structural and catalytic roles. Divalent metal ions such as Mg, Mn, and Zn are often, but not always, obligatory cofactors for ribozymes and deoxyribozymes. We recently described the 10MD5 deoxyribozyme as an example of a hig...

Two experiments were conducted to assess nutrient partitioning in coffee (Coffea arabica cv. Typica land race Guatemala) infected with Meloidogyne konaensis. Nutrient levels were quantified from soil, roots, and leaves. In the first experiment, 500-cm3 aliquants of a Kealakekua Andisol were infested with four initial population densities of M. konaensis ranging from 0 to 1,500 freshly hatched s...

To investigate the correlations among seminal plasma Magnesium (Mg), Phosphorus (P), Potassium (K), Calcium (Ca), Chromium (Cr), Manganese (Mn), Iron (Fe), Copper (Cu), Zinc (Zn), Selenium (Se), Molybdenum (Mo) and Iodine (I) concentrations and semen parameters [1– 15]. 500 fertile and 1000 infertile males provided a standardized semen specimen. Total Magnesium (Mg), Phosphorus (P), Potassium (...

altogether 20 groundwater samples were collected around the lakan pb and zn mine in iran. samples were analyzed for 8 constituents including fe, pb, hg, mn, zn, cn, so4 and cl using standard method. the results show that the average concentrations of constituents were 0.01, 0.60, 0.10, 0.01, 0.40, 35, 0.01 and 5.95 mg/kg for fe, mn, pb, zn, hg, so4, cn and cl, respectively. the computed contami...

this study was carried out to determination of in vitro binding capacity of organic (wheat and barley) and inorganic (perlite) sources for mn, zn, cu, and fe. for this reason wheat and barley were analyzed chemically for moisture, protein, ash, and ether extract, total carbohydrate, ndf, adf, adl, crude fiber, viscosity, cellulose, and total dietary fiber. the in vitro mineral binding capacity ...

The carbon-encapsulated, Mn-doped ZnSe (Zn1 xMnxSe@C) nanowires, nanorods, and nanoparticles are synthesized by the solvent-free, one-step RAPET (reactions under autogenic pressure at elevated temperature) approach. The aspect ratio of the nanowires/nanorods is altered according to the Mn/Zn atomic ratio, with the maximum being observed for Mn/Zn1⁄4 1:20. A 10–20 nm amorphous carbon shell is ev...

We introduce two methods for the visualization of phosphorylated proteins using alkoxide-bridged dinuclear metal (i.e. Zn(2+) or Mn(2+)) complexes as novel phosphate-binding tag (Phos-tag) molecules. Both Zn(2+)- and Mn(2+)-Phos-tag molecules preferentially capture phosphomonoester dianions bound to Ser, Thr, and Tyr residues. One method is based on an ECL system using biotin-pendant Zn(2+)-Pho...

The crystal and molecular structures of [bis(5-chloro-2methoxybenzoate)tetraaquamanganese(II)], [pentaaqua(5-chloro-2-methoxybenzoato)cobalt(II)] (5chloro-2-methoxybenzoate), [pentaaqua(5-chloro-2-methoxybenzoato)nickel(II)] (5-chloro-2methoxybenzoate) and [aquabis(5-chloro-2-methoxybenzoate)zinc(II)] monohydrate were determined by a single-crystal X-ray analysis. Mn(H2O)4L2 (where L = C8H6ClO3...

Mn 3d electronic states in the dilute magnetic semiconductor Zn(1-x)Mn(x)S (x = 0.1-0.3) are studied using soft x-ray emission (XES) measurements and density functional theory (DFT). Mn L(2,3) emission spectra of Zn(1-x)Mn(x)S (x = 0.1-0.3) suggest that the Mn impurities do not form clusters in the host ZnS lattice, in agreement with previous models. A shift in the position of a Mn L(3) XES fea...

BACKGROUND & OBJECTIVES Relationship of trace elements with obesity and diabetes is complex, alterations in their metabolism can be induced by the diseases and their complications. To study the role of the trace elements in diabetes and obesity, serum trace elements levels (Cr, Se, Fe, Zn, Cu and Mn) were measured in obese women with or without diabetes as well as healthy women. Further, correl...