Many-body perturbation theory is implemented in order to calculate the isotope shifts of $4s$, $4p_{1/2}$, $4p_{3/2}$, $3d_{3/2}$, and $3d_{5/2}$ energy levels Ca$^+$, for even isotopes $A=$40, 42, 44, 46, 48. The results are presented mass shift field shift, as well higher-order shifts, quadratic nuclear polarization correction, cross term between shifts. Additionally, we examine King-plot non...

Vegetation plays a significant role in the isotopic fractionation of rainwater during rainfall partitioning through canopy into throughfall and stemflow. Most studies focus on composition throughfall, whereas that stemflow has been studied much less frequently. Moreover, only three to date have investigated at intra-storm scale. Therefore, knowledge shift between throughfall/stemflow fine resol...

The aerial parts of Tephrosia carrollii afforded two chromene chalcones. Their structures and stereochemistry were established by spectroscopic methods. The structure of oaxacacin was revised and confirmed by X-ray diffraction. In this paper, we describe the isolation of the chalcone known as "oaxacacin" and the new chalcone named epoxyobovatachalcone. The compound der. oaxacacin was found to b...

The magnitude and orientation of the principal components of the carbonyl carbon chemical shift tensor of a typical aryl aldehyde, 3,4-diben~yloxybenzaldehyde-~~C,~H,, 1, have been determined from the analysis of I3C NMR spectra of static powder samples obtained at 4.7 and 9.4 T. The principal components of the carbon shielding tensor of formaldehyde, 2, have been calculated from the experiment...