نتایج جستجو برای: 4 thiadiazole
تعداد نتایج: 1304406 فیلتر نتایج به سال:
Reaction of sodium salt of allyl alcohol with 2-chloro-5-phenyl- l,3,4-thiadiazole gave 2-allyloxy-5-phenyl-1,3,4-thiadiazole 2. Compounds 4a and 4b could be obtained through the reaction of nitrone 3 with 2. Reaction of compound 2 with nitrone 5 afforded the final compound 6. Antifungal activity of all compounds was less than ketoconazole
A regioregular terpolymer that combines electron-deficient diketopyrrolopyrrole and benzothiadiazole units with an electron-rich dithienopyrrole unit is presented. In solar cells, the terpolymer affords an open circuit voltage of 0.52 V and a power conversion efficiency of 3.7% with a spectral response up to 1050 nm.
A potential therapeutic strategy for targeting cancer that has gained much interest is the inhibition of the ATP binding and ATPase activity of the molecular chaperone Hsp90. We have determined the structure of the human Hsp90α N-terminal domain in complex with a series of 5-aryl-4-(5-substituted-2-4-dihydroxyphenyl)-1,2,3-thiadiazoles. The structures provide the molecular details for the activ...
A bi-thiadiazole derivative, 5,5'-bis(4- tetradecyloxyphenyl)-2,2'-bi-1,3,4-thiadiazole (BTD-14), was revealed to exhibit an extremely stable thermotropic SmC phase and very interesting aggregation behavior in solutions. H- and J-aggregates could be formed simultaneously in chloroform solutions of BTD-14 with moderate concentration (10(-4) M), and the population of J-aggregates enlarges during ...
Benzyl and chlorobenzyl substituted 1, 3, 4-thiadiazole imine derivatives have been prepared by refluxing aromatic aldehyde imine derivatives and benzyl chloride/ 4-chloro benzyl chloride in ethanolic potassium hydroxide. The structures of the compounds have been determined by spectral and chemical methods. The anticonvulsant activity has been carried out using Karl et al. method. All the repor...
Abstract A series of 1,3,4-thiadiazole derivatives were designed and synthesized using N -(4-nitrophenyl)acetohydrazonoyl bromide 1-[3,5-dimethyl-1-(4-nitrophenyl)-1 H -pyrazol-4-yl]ethan-1-one as starting materials. The treatment with methyl hydrazinecarbodithioate or hydrazinecarbothioamide afforded 2-[1-[5-methyl-1-(4-nitrophenyl)-1 -pyrazol-4-yl]ethylidene]hydrazine derivatives. targeted 1,...
Eight novel compounds were prepared by reaction of 5-(bromo- propoxyphenyl)-10,15,20-triphenylporphyrin with oxazole thiols, 1,3,4-oxadiazole thiols and 1,3,4-thiadiazole thiols, and their structures confirmed by UV-vis, IR, 1H-NMR, MS and elemental analysis. The assessment of indirectly measured 1O(2) production rates against 5,10,15,20-tetraphenyl porphyrin (H(2)TPP) were described and the re...
In this study, a novel organic depressant maleyl 5-amino-1,3,4-thiadiazole-2-thiol (MATT) was synthesized and utilized as galena in the flotation separation of molybdenite galena. The results test indicated that MATT exhibited an excellent depression ability on but barely influenced pH range 6.0–11.0. Zeta potential suggested preferentially adsorbed surface. UV-visible spectroscopy analysis sto...
OBJECTIVE(S) Nowadays, cancer is an important public health problem in all countries. Limitations of current chemotherapy for neoplastic diseases such as severe adverse reactions and tumor resistance to the chemotherapeutic drugs have been led to a temptation for focusing on the discovery and development of new compounds with potential anticancer activity. MATERIALS AND METHODS A new series o...
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