Article history: Available online 17 July 2008

Rate constants for release of Mg +, glucose -phosphate, glucose 6-phosphate, and glucose 1 ,6-diphosphate from the catalytically active complex under initial velocity conditions together with rate constants for dissociation of the Mg 2+ complexes of phosphoand dephosphoenzyme are used to define the order of addition and release of the above species during the phosphoglucomutase reaction. Althou...

3 Proof of Theorem 1 9 3.1 Estimation of the g1 term. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12 3.2 Estimation of the g3 term. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13 3.3 Estimation of the g2 term. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13 3.4 Putting everything together. . . . . . . . . . . . . . . . . . . . . ....