نتایج جستجو برای: alkene

تعداد نتایج: 1831  

Journal: :Chemical communications 2010
Takuya Ozawa Hiroaki Horie Takuya Kurahashi Seijiro Matsubara

Intermolecular [2+2+1] cycloaddition which incorporates an alkyne, an isocyanate, and an alkene into a γ-butyrolactam proceeds with nickel catalyst.

Journal: :Chemical communications 2006
Béatrice Quiclet-Sire Samir Z Zard

The reaction of hydrazones with iodine/base leads to diazo intermediates that can be trapped by an internal alkene or alkyne.

Journal: :Angewandte Chemie 2010
Wei Li Nan Chen John Montgomery

Catalytic reductive coupling processes have been developed in numerous contexts as a strategy for the regioand stereoselective installation of alkenes. The direct coupling of a polar p system with a relatively nonpolar p system is often a successful strategy for selectively accomplishing synthetically desirable heterocouplings while avoiding undesired homocoupling of either reagent. For example...

2010
Rajamani Gounder Enrique Iglesia

Brønsted acid sites in zeolites (H-FER, H-MFI, H-MOR) selectively hydrogenate alkenes in excess H2 at high temperatures (>700 K) and at rates proportional to alkene and H2 pressures. This kinetic behavior and the De Donder equations for non-equilibrium thermodynamics show that, even away from equilibrium, alkene hydrogenation and monomolecular alkane dehydrogenation occur on predominantly uncov...

Journal: :Polymer 2022

We report the synthesis of cyclic cobaltocenium olefins (cationic cobaltocenophane or ansa-cobaltocenium). This is prepared by ring-closing metathesis (RCM) diallyl cobaltocenium, which isomerizes into two different dienes. The isomerization terminal alkene at higher temperature results in thermodynamically more stable internal alkene, supported computational calculation. RCM these isomers prod...

Journal: :Journal of Biological Chemistry 1997

Journal: :Journal of the American Chemical Society 2018

Journal: :Molecules 2017
Mohamed Touaibia Eva-Maria Krammer Tze C Shiao Nao Yamakawa Qingan Wang Anja Glinschert Alex Papadopoulos Leila Mousavifar Emmanuel Maes Stefan Oscarson Gerard Vergoten Marc F Lensink René Roy Julie Bouckaert

Antagonists of the Escherichia coli type-1 fimbrial adhesin FimH are recognized as attractive alternatives for antibiotic therapies and prophylaxes against acute and recurrent bacterial infections. In this study α-d-mannopyranosides O- or C-linked with an alkyl, alkene, alkyne, thioalkyl, amide, or sulfonamide were investigated to fit a hydrophobic substituent with up to two aryl groups within ...

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