In this paper, rutile TiO2 nanorod arrays are fabricated by a template-free method and proposed as a promising anode for aqueous Li-ion battery. The as-prepared TiO2 nanorod arrays exhibited reversible Li-ion insertion/extraction ability in aqueous LiOH electrolyte. Moreover, galvanostatic charge/discharge test results demonstrated that the reversible capacity of TiO2 nanorods could reach about...