Six unsymmetrical diorganyltellurium(IV) dichlorides RR'TeCl2 (where R= phenacyl-, 1-naphthacyl-, and styrylacyl- and R' = p-methoxyphenyl, p-hydroxyphenyl-, and 3-methyl-4-hydoxyphenyl-) were tested for their antibacterial activity against gram-positive (Bacillus subtilis ATCC 6633 and Staphylococcus aureus ATCC 25923) and gram-negative (Escherichia coli ATCC 25922. Pseudomonas aeruginosa ATCC...

The electronic spectrum o f Cp2TiSs shows a long-wavelength absorption at Amax = 492 nm which is assigned to the lowest-energy S52~ ^ T i IV ligand-to-metal charge transfer (LM CT) transition. The photolysis o f the complex in CH2CI2 leads to the formation o f Cp2TiCl2 and elemental sulfur. It is suggested that LM CT excitation initiates a reductive elimination with the extrusion o f S5 while t...

9 Titanocene and zirconocene complexes with a phenyl or I-naphthyl substituent in one ,B-position of each Cs-ring ligand and with an interannular tetramethylethanoor dimethylsilano-bridge have been prepared. Racemic complex isomers, which are formed together with varying amounts of their meso isomers, were separated from the latter and characterised by lH NMR spectroscopy and X-ray crystallogra...

An operationally simple, convenient, and mild strategy for the synthesis of triazole-substituted titanocenes via strain-driven 1,3-dipolar cycloadditions between azide-functionalized titanocenes and cyclooctyne has been developed. It features the first synthesis of titanocenes containing azide groups. These compounds constitute 'second-generation' functionalized titanocene building blocks for f...

The recently reported cationic titanocene complex [Cp2TiMe(OH2)](+) was subjected to detailed computational studies using density functional theory (DFT). The calculated NMR spectra revealed the importance of including the anion and the solvent (CD2Cl2) in order to calculate spectra which were in good agreement with the experimental data. Specifically, two organic solvent molecules were require...

Cyclotriarsanes are rare and described herein is a scalable synthetic protocol towards aryl-substituted derivatives. Their reactivity [Cp2Ti(C2(SiMe3)2)], affording titanocene diarsene complexes, N-heterocyclic carbenes (NHCs) discussed.

BACKGROUND Hormone-refractory breast cancer metastatic to bone is a clinically challenging disease associated with high morbidity, poor prognosis, and impaired quality of life owing to pain and skeletal-related events. In a preclinical study using a mouse model of breast cancer and bone metastases, Ra-223 dichloride was incorporated into bone matrix and inhibited proliferation of breast cancer ...

We present empirical evidence for a radiative cooling time for the Io plasma torus that is about a factor of ten less than presently accepted values. We show that brightness fluctuations of the torus in the extreme ultraviolet (EUV) at one ansa are uncorrelated with the brightness at the other ansa displaced in time by five hours, either later or earlier. Because the time for a volume of plasma...