~-Amino acid oxidase has been shown to have a critical temperature of 12-14’. Around this temperature it has been shown that a reversible change in protein conformation occurs; the change in enthalpy of the transition has been calculated as 78,000 cal per mole. Other parameters have also been shown to change on either side of this temperature; these include sedimentation constant, ultraviolet a...

The activities of acetylcholinesterase (ACHE) and butyrylcholinesterase (BuChE) in rat brain capillaries were measured as a function of temperature. Arrhenius plots of the data revealed that AChE exhibits a biphasic Arrhenius plot with a distinct break (transition temperature) at about 15.2 kcal/mol. In contrast, BuChE did not show evidence of discontinuity. BuChE showed an activation energy hi...

The temperature sensitivity of enzymes responsible for organic matter decomposition in soil is crucial for predicting the effects of global warming on the carbon cycle and sequestration. We tested the hypothesis that differences in temperature sensitivity of enzyme kinetic parameters V max and K m will lead to a canceling effect: strong reduction of temperature response of catalytic reactions. ...

The gliding movements of certain Cyanophyceae, Thiobacteriales, and gregarines provide relatively uncomplicated types of comparable activities suitable for quantitative observation. In spite of much discussion, little is known as to the mechanism of this sort of progression. Interpretations have been advanced by a number of writers, t but data required for formulation of a theory of this sort o...

The purpose of this study was to predict the stability of octreotide in a mixed infusion containing sodium bisulfite (SBS). In aqueous solution the hydrolysis of octreotide was found to be accelerated by pH, and by increasing concentrations of SBS. Equations for the degradation rate constants (kobs) of pH and SBS were derived. The fractional rate constants were estimated by the nonlinear least-...

The influence of calcination time on the phase transformation and crystallization kinetics of anodized titania nanotube arrays was studied using in-situ isothermal and non-isothermal synchrotron radiation diffraction from room temperature to 900 °C. Anatase first crystallized at 400 °C, while rutile crystallized at 550 °C. Isothermal heating of the anodized titania nanotubes by an increase in t...

The anomalous temperature dependence of protein folding has received considerable attention. Here we show that the temperature dependence of the folding of protein L becomes extremely simple when the effects of temperature on protein stability are corrected for; the logarithm of the folding rate is a linear function of 1/T on constant stability contours in the temperature-denaturant plane. This...

A non-Arrhenius model based on the Mittag-Leffler function has been conceived as a basic concept. This approach allows modelling both sub-Arrhenius and super-Arrhenius behaviours giving rise to modified temperature integrals.

The extracts of Piper sarmentosum, a medicinal plant, are being used to prepare phytopharmaceuticals while the information about chemical kinetics of constituents of the extract is unavailable to assign precise shelf life (t90) and find optimum storage conditions of the product for patient safety, and to avoid economic repercussions of launching an unstable product. The extract was exposed to t...

An approximate formula for the frequency of oscillations is theoretically derived for skeleton models for electrochemical systems exhibiting negative differential resistance (NDR) under conditions close to supercritical Hopf bifurcation points. The theoretically predicted omega infinity (k/R)1/2 relationship (where R is the series resistance of the cell and k is the rate constant of the charge ...