The trivalent arsenic glutathione complexes arsenic triglutathione, methylarsonous diglutathione, and dimethylarsinous glutathione are key intermediates in the mammalian metabolism of arsenite and possibly represent the arsenic species that are transported from the liver to the kidney for urinary excretion. Despite this, the comparative stability of the arsenic-sulfur bonds in these complexes h...

Six arsenic species [arsenate, arsenite, arsenocholine, arsenobetaine, monomethyl arsonic acid, and dimethyl arsinic acid] present in human urine were determined using ion-exchange chromatography combined with inductively coupled plasma mass spectrometry (IC-ICP-MS). Baseline separation was achieved for all six species as well as for the internal standard (potassium hexahydroxy antimonate V) in...

Since Babagorgorfountain in the Ghorveh city of Kurdistan province is located in the arsenic belt of Iran, to raise awareness about the quality of drinking water from this fountain the concentration of arsenic and other heavy metals as well as other physicochemical parameters were investigated to protect the public health. In this study, water samples were collected from Babagorgorfountain. Ars...

BACKGROUND Millions of people worldwide consume arsenic-contaminated rice; however, little is known about the uptake and bioavailability of arsenic species after arsenic-contaminated rice ingestion. OBJECTIVES In this study, we assessed arsenic speciation in greenhouse-grown and supermarket-bought rice, and determined arsenic bioavailability in cooked rice using an in vivo swine model. RESU...

Direct measurement of arsenic release requires a good sampling and analysis procedure in order to capture and detect the total amount of metals emitted. The literature is extensively reviewed in order to evaluate the efficiency of full field-scale and laboratory scale techniques for capturing particulate and gaseous emissions of arsenic from the thermo-chemical treatment of different sources of...

(1) Arsenic fungi are more numerous than was previously supposed. Some saprophytic species common in the soil are active in the production of arsenical gases. (2) Arsenic tolerant forms include many species which do not decompose arsenic compounds with the evolution of gases. (3) Arsenical substances carried to the soil come in contact with decomposing agents, which tend to break them into vola...

The biocomplexity of sediment communities along a 120m transect near an arsenic-rich, shallow marine hydrothermal vent at Tutum Bay, Papua New Guinea was thoroughly examined. A count of macroand meiofaunal organisms was combined with bacterial and eukaryotic SSU rRNA gene surveys to assess biodiversity. Each site along the transect had distinct microbial communities. Near-vent sites were more s...

Enzymatic extraction methods were evaluated with classical extraction approaches for the determination of arsenic in food. The extraction efficiency for total arsenic was determined by analysing CRM materials DORM-3 fish protein, NIES 106 rice flour and GBW10015 spinach. These were compared with total arsenic concentration determined using microwave-assisted acid digestion and ICP-MS. The total...

OBJECTIVES The purpose of this study was to develop an analytical method for the simultaneous determination of inorganic arsenic [As(III) and As(V)] and monomethylarsonic acid (MMA) in urine by gas chromatography-mass spectrometry (GC-MS) for the biological monitoring of exposure to inorganic arsenic. METHODS Arsenic compounds (after reduction of arsenic to the trivalent state) were derivatiz...

Although there have been numerous studies on arsenic in low-trophic-level marine organisms, few studies exist on arsenic in marine mammals, seabirds, and sea turtles. Studies on arsenic species and their concentrations in these animals are needed to evaluate their possible health effects and to deepen our understanding of how arsenic behaves and cycles in marine ecosystems. Most arsenic in the ...